纯铝微弧氧化膜层性能的研究-材料学专业论文.docxVIP

河北工业大学硕士学位论文 河北工业大学硕士学位论文 纯铝微弧氧化膜层性能的研究 纯铝微弧氧化膜层性能的研究 万方数据 万方数据 万方数据 万方数据 摘 要 微弧氧化技术是一种新型的表面处理技术，是在阀金属表面通过微等离子体放 电，进行复杂的等离子化学、电化学和热化学反应，原位生成一层均匀绝缘的氧化陶 瓷层的工艺，可极大地改善铝及其合金的性能。 本文研究了电解液组分对铝的微弧氧化膜层表面形貌、厚度、结合强度以及耐大 气腐蚀性能的影响。基于对负向电参数在膜层生长中作用机理的探讨，研究了负向电 流密度以及负向占空比对成膜的影响规律。研究结果表明，在已得到的工艺参数基础 上，电解液中加入 4.5mL/LC3H8O3，溶液电导率为 16.5mS/cm，负向电流密度为 9A/dm2， 负向占空比为 30%的条件下，可得到膜层孔隙率低，表面质量好，与基体结合良好以 及耐大气腐蚀的综合性能较好的膜层。 通过对溶质离子在微弧氧化过程中的作用机理研究表明：在微弧氧化反应初期， 溶质离子促使铝基体表面形成易失稳的阻挡膜层；膜层生长时，为膜层生长的击穿放 电提供条件；在生长后期，溶质离子主要是为陶瓷膜生长提供氧等膜层所需元素，最 终生成陶瓷结构的膜层。 关键字：纯铝 微弧氧化 陶瓷膜 结合强度 耐腐蚀性能 I ABSTRACT Micro-arc oxidation is a new surface technology producing ceramic coating on valve metals. It is a complex reaction process, involving plasma chemical and electrochemical, thermal chemical reactions. With this method, ceramic coatings can be directly formed on the surface of Al alloys, and the surface properties can be improved considerably. In this paper, the effects of electrolyte composition on surface morphologies, thickness, bonding strength and corrosion resistance property of coatings were investigated. Meanwhile, the effects of cathodic current density and cathodic duty ratio on the form of film were analyzed, due to the seldom research of mechanism of cathodic electric parameters. On the basis of original parameters, the coatings exhibit lower porosity and better surface appearance by the process composed of 4.5mL/L C3H8O3 in the electrolyte, conductivity 16.5mS/cm, cathodic current density 9A/dm2 and cathodic duty ratio 30%. In addition, the better bonding strength and corrosion resistance can be received. The mechanism of solute ions on the formation and growth of the ceramic coating was studied in the meantime. The function of solute ions is to form the unstable blocking layer on the surface of the aluminum alloy during the initial stage of film formation. In the same time, the blocking layer provide precondition. In the ceramic’s later growth, solute ions provide the indispensable elements such as oxyge