GMA改性水性醇酸树脂的合成及应用-腐蚀科学与防护技术.PDFVIP

第29 卷 第3 期 腐蚀科学与防护技术腐蚀科学与防护技术 Vol. 29 No. 3 2017 年5 月 CORROSION SCIENCE AND PROTECTION TECHNOLOGY Mar 2017 GMA 改性水性醇酸树脂的合成及应用 李至秦 魏金伯 杨名亮 苏雅丽 付 率 方大庆 厦门双瑞船舶涂料有限公司 厦门 361101 摘要 以豆油、苯甲酸、邻苯二甲酸酐、偏苯三甲酸酐及三羟甲基丙烷为主要原料，采用熔融盐法合成水性醇酸 树脂，并用甲基丙烯酸缩水甘油酯(GMA) 对其进行改性。通过Fourier 变换红外光谱，扫描电子显微镜和差热 扫描量热仪等仪器对改性树脂进行表征。结果表明，经GMA 改性后的醇酸树脂吸水率明显下降。以GMA 改 性醇酸树脂为原材料，开发了一种耐水型水性醇酸涂料，其耐盐雾时间可达2000 h 。 关键词 醇酸树脂 水性树脂 GMA 金属防腐 中图分类号 TQ633 文章编号 1002-6495(2017)03-0275-07 Preparation and Performance of GMA Modified Waterborne Alkyd Resin LI Zhiqin, WEI Jinbo, YANG Mingliang, SU Yali, FU Shuai, FANG Daqing Xiamen Sunrui Ship Coating Co., Ltd., Xiamen 361101, China Correspondent: FANG Daqing, E-mail:163.com Supported by Development and Industrialization of Ship and Marine Green Long-lasting Anti-corrosion Coating (2014BAE 12B01) Manuscript received 2016-07-11, in revised form 2017-02-16 ABSTRACT Waterborne alkyd resin was prepared via molten salt process with soybean oil, benzoic acid, phthalic anhydride, trimellitic anhydride and trimethylolpropane as raw materials, and then modified with glycidyl methacrylate (GMA). The prepared alkyd resin was characterized by FT-IR, DSC and SEM. The result showed that the water absorption of the alkyd resin decreased after GMA modification. A kind of waterproof waterborne alkyd coating was prepared based on GMA modified alkyd resin, which can withstand a long term salt spray test up to 2000 h.