难分解铌钽矿高浓氢氧化钾浸出机理研究-高校化学工程学报.PDF

19 2 No.2 Vol.19 2005 4 Journal of Chemical Engineering of Chinese Universities Apr. 2005 1003-9015(2005)02-0148-08 1,2 1 1 , , (1. 100080; 2. , 361005) -- 1+2(1-X )-3(1-X )2/3=kt -1 72.2kJ mol (SEM) X- (EDAX) ()([(Ta,Nb)6O19]8-) TF111.313 TG146.416 O614.512 O614.513 TQ028.96 A Study on the Leaching Mechanism of Refractory Niobium-tantalum Ore by Concentrated Potassium Hydroxide 1,2 1 1 ZHOU Hong-ming , ZHENG Shi-li , ZHANG Yi (1. Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100080,China; 2. Department of Chemical Engineering and Biological Engineering, School of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China) Abstract: The leaching mechanism of niobium from a refractory niobium-tantalum ore by concentrated potassium hydroxide was studied. The effects of stirring speed, reaction temperature, mass ratio of alkali-to-ore, initial potassium hydroxide concentration and particle size on the leaching rate of niobium were reported. The results show that the leaching rate is direct proportional to the inverse square of particle diameter, and the experimental data of the leaching rate are fit to the Crank-Ginsting-Braunshtein’s diffusion-through-layer-reaction-control modelthat is: 1+2(1-X )-3(1-X )2/3=kt. Accor