《化学发光材料双（2,4,6三氯苯基）草酸酯的合成》-毕业论文（设计）.docVIP

任军利：化学发光材料双（2,4,6-三氯苯基）草酸酯的合成 PAGE \* MERGEFORMAT IV 化学发光材料双（2,4,6三氯苯基）草酸酯的合成 （安徽工程大学机电学院 化工2071班 3072109111） 摘 要 研究化学发光材料化学发光材料双（2,4,6-三氯苯基）草酸酯的合成方法，探索其合成的最佳实验条件。以苯酚、双氧水、浓盐酸、氯化镁为原料，制备2,4,6-三氯苯酚，将生成的2,4,6-三氯苯酚溶于苯中，与草酰氯合成双（2,4,6-三氯苯基）草酸酯。改变实验条件进行实验，重点考察反应物摩尔比、反应时间、反应温度、催化剂对双（2,4,6三氯苯基）草酸酯产率的影响。实验结果表明，双（2,4,6-三氯苯基）草酸酯合成的最佳实验条件是：n(草酰氯):n(2,4,6三氯苯酚)=1:1.9，反应时间为30分钟，反应温度室温即可。以三氯化铁为催化剂反应对合成影响不大。 关键词:2,4,6-三氯苯酚；合成； 双（2,4,6-三氯苯基）草酸酯； 产率 Synthesis of bis (2,4,6 trichlorophenyl) oxalate used as Chemiluminescent material Ren junli (Anhui polytechnic university,Chemical Engineering and Technology 2071 3072109111) Abstract Explore the synthetic method of chemiluminescent material bis (2,4,6-trichloro benzyl)oxalate, and discover the best experimental conditions for their synthesis. chlorine from the reaction of hydrogen peroxide and concentrated hydrochloric acid, produces 2,4,6- trichlorophenols With the phenol. 2,4,6- trichlorophenols dissolve in the benzene, Gathers the bis (2,4,6-trichlorobenzyl)oxalate with the oxalyl chloride. experiment by changing Experimental conditions, discussed production rate of bis (2,4,6- trichloro benzyl)oxalate in influencing reactant mole with mole of ratio、 the reaction time、reaction temperature、 the catalyst and so on .the experiment shows,the best experiment conditionds of bis (2,4,6 trichloro benzyl)oxalate synthesis, oxalyl chloride and an 2,4,6 trichlorophenols mole of ratio is 1:1.9, The time of reaction is 30 minutes, The best temperature is under room temperature. It is not a remarkable influence in takeing the iron catalyst. Key words : 2,4,6 – Trichlorophenol ; Synthesis; bis (2,4,6- trichloro benzyl)oxalate; Production rate 目 录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc295832629 引言 PAGEREF _Toc295832629 \h - 3 - 第1章 HYPERLINK \l _Toc295832630 实验部分 PAGEREF _Toc295832630 \h - 3 - HYPERLINK \l _Toc295832631 1.1主要的试剂和样品 PAGEREF _Toc295832631 \h - 3 - HYPERLINK \l _Toc295832632 1.2 主要的设备和仪器 PAGEREF _T