《聚乙烯接枝马来酸酐的制备》-毕业论文（设计）.doc

PAGE PAGE 2 本科毕业论文(设计) 题 目：聚乙烯接枝马来酸酐的制备 学 院： 应用技术学院 专 业： 高分子材料与工程 姓 名： 张小姗 指导教师： 张来祥老师 2011年 聚乙稀接枝马来酸酐的制备 张小姗 （青岛大学 应用技术学院 山东 青岛） 摘要 聚乙烯它本身具有比较好的物理机械性能和加工性能，因而被作为通用塑料广泛的应用。采用溶液接枝与反应性挤出接枝来制备PE-g-MAH。对接枝与未接枝、接枝率不同的接枝物分别进行拉伸与压缩及冲击性能测试，比较得出力学性能最佳的方案。实验表明：与普通聚乙烯比较,被接枝后的聚乙烯一般采用干法和湿法但是接枝马来酸酐聚乙烯只适合干法，利用搅拌机和高速混炼机并加入分散介质进行充分混合加强其分散性，从而能有效提高PE材料的拉伸强度、弯曲强度和冲击强度的同时保持了聚乙烯基体的刚性，通过实验也能进一步说明马来酸酐含量在复合材料中的分散性是有着非常重要的意义。 关键词 聚乙烯、 接枝率、性能测试 Abstract Polyethylene it itself has better physical and mechanical properties and processing properties, they have been widely used as a general-purpose plastic. By solution grafted and reactive extrusion grafted to preparation PE - g - MAH. Docking branch and not graft copolymerization, grafted rate of different graft is stretched and compressed respectively comparing the performance test, and impacts that optimal mechanical property solutions. Experiment shows that compared with ordinary polyethylene, be grafted the polyethylene generally adopted after dry and wet but grafting maleic anhydride polyethylene only suitable for dry, using blender and high-speed mixing rubber machine and join scattered media are fully mixing strengthen its dispersion, which can effectively enhance the PE material tensile strength, bending strength and impact strength while keeping the polyethylene matrix rigidity, through experiment could also further shows with maleic anhydride content in the dispersion of composite materials have very important significance is. Key words Polyethylene, graft rate, performance testing 目录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc294604320 摘要 PAGEREF _Toc294604320 \h 2 HYPERLINK \l _Toc294604321 关键词 PAGEREF _Toc294604321 \h 2 HYPERLINK \l _Toc294604322 目录 PAGEREF _Toc294604322 \h 4 HYPERLINK \l _Toc294604323 引言 PAGEREF _Toc294604323 \h 5 HYPERLINK \l _Toc294604324 1. 相容剂在聚合物中的分散 PAGEREF _Toc294604324 \h 6 HYPERLINK \l _Toc294604325 1.1相容剂简介及作用机理 PAGEREF _Toc294