滇池沉积物磷负荷及沉积物-水界面控释材料研发-地质工程专业论文.docxVIP

三 三 峡 大 学 全 日 制 专 业 学 位 硕 士 学 位 论 文 PAGE III万方数据 PAGE III 万方数据 烧温度为 600℃。 4）改性实验结果表明，混合红土后能够降低材料的吸附解吸平衡浓度（EPC0）， 结合材料最大吸附量、EPC0 及滇池水质现状，确定沉积物与混合物的最佳质量配比 范围为 50%~90%。添加聚合氯化铝及与玉米芯改性后，材料空隙及对磷酸盐的结合 能力增强，材料对磷酸盐的吸附容量增加，约为改性前的 3 倍。 5）改性材料对磷酸盐的吸附等温线符合 Langmuir 非线性模型。材料对磷酸盐的 吸附容量随温度的升高而增大，其吸附过程吸热，反应为自发过程。材料对磷酸盐的 去除率随着溶液 pH 值的增加而降低。 6）室内静态模拟实验表明，材料能够增强沉积物-水界面 Eh 值，使覆盖界面保 持较高的 DO 浓度，能够有效控制沉积物-水界面磷负荷。改性材料用于控制滇池沉 积物磷负荷的建议投加用量为 0.23~9.71kg/m2。 关键词：磷负荷 磷形态 沉积物-水界面 控释材料 滇池 Abstract Eutrophation is a serious problem that has attracted worldwide attention from scientists and government agencies. Internal P-loading, which is negligible for the restoration of shallow lakes, may delay the recovery of lakes following the reduction of external P-loading sources. Determine and quantification the internal P-loading is essential for lake internal loading management. A novel sediment-water interface phosphorus flux control material (PFCM) was synthesized by use of the sediments of Lake Dianchi and its local red soil. The main results are as follows: The average content of total phosphorus in the surface sediment of Lake Dianchi was around 2184.39±579.09 mg/kg, and there was 5.2×104t phosphorus in the top 15cm sediments. Calcium bound P (HCl-P) was the main fraction of sediment phosphorus, and it accounted for 40.63% of TP. The potential mobile phosphorus represented 5.89~23.99% of TP, among which，redox sensitive bound P (BD-P),metal oxide bound P (NaOH-rP) and organic P (NaOH-nrP) was 6.14%, 20.45% and 5.36% of TP respectively. In the surface sediments, the rank order of P-fractions was HCl-PNaOH-rP NaOH-nrPRes-PBD-P. Diffusive flux of soluble reactive phosphorus(SRP) across the sediment-water interface (SWI) of Lake Dianchi was -0.296~0.489mg/(m2·d), and the dissolved organic phosphorus release flux was -1.605~3.644mg/(m2·d). Sediment was a significant source of phosphorus in the annual budget for Lake Dianchi. Diffusive flux of phosphorus from Lake Dianchi sediments contributes ~9.39% of