隔板塔在过程强化中的应用研究-化学工程专业论文.docxVIP

摘 要 精馏是一种应用非常广泛的化工单元操作，但是精馏过程的能耗较大。隔板 塔作为完全热耦合精馏塔的一种特殊结构，实现了用一个精馏塔完成两个常规塔 所能完成的分离任务，因而能够降低设备投资费用和减少占地面积，同时还可以 降低能耗。 本文在 Aspen 模拟软件的基础上着重研究了隔板塔的性能及其在物系分离 上的应用，并以分离三组分醇类混合物为例，模拟了物系在隔板塔中的浓度和温 度分布，并探讨了进料组成、回流比、汽液相分配比和隔板位置对三组分分离效 果的影响。为验证模拟的准确性，本文还进行了小试实验，实验结果与模拟的结 果基本保持一致，再次证明了隔板塔在物系分离上的可行性。 本文还就隔板塔在其他方面上的应用进行了探讨，重点研究了隔板反应精馏 和隔板萃取精馏。在隔板反应精馏中，研究了乙酸甲酯水解生成甲醇和乙酸这一 反应，分析了水酯摩尔比、回流比、液相分配比对乙酸甲酯转化率和甲醇纯度的 影响，总结出了最优操作参数。对于隔板萃取精馏的研究，本文加入了常规萃取 流程，在相互比较中发现隔板萃取精馏能够消除返混现象，而且其浓度、流量和 温度分布更加合理，同时还证实了隔板萃取精馏能够节能达 20%以上。 关键词：隔板塔；模拟；反应精馏；萃取精馏；节能 ABSTRACT Distillation, which has high energy consumption, is widely used unit operation in chemical industry. As a special structure of fully thermally coupled distillation column, DWC can reduce energy consumption significantly, while also reducing the cost of equipment investment and floor space. This paper focused on research in the performance of DWC and the separation of the material on the basis of the Aspen simulation software, made the separation of three component alcohol mixture as a example, simulated the concentration and temperature distribution in the DWC, and introduced the effect of feed composition, reflux ratio, vapor-liquid split ratio and bulkhead location on the separation results. To verify the accuracy of the simulation, a small pilot experiment was also conducted, and the experimental results were basically consistent with the simulation results, which proved the feasibility of the DWC on the separation of the mixture once again. This paper also discussed the application of DWC in other areas, especially in the RDWC and EDWC. In the research of RDWC, the hydrolysis reaction of methyl acetate generated to methanol and acetic acid was studied, then the influences of reflux ratio, liquid distribution ratio and molar ratio of ester in water on the conversion rate of methyl acetate and the purity of the product were investigated, the optimum operation parameters was obtain finally. In order to analysis EDWC better, the conventional