改性壳聚糖对地下水重金属吸附性能研究-环境科学专业论文.docxVIP

静态等温平衡吸附研究显示：交联壳聚糖对 Zn2+、Cr6+吸附均符合 Langmuir 吸附等温模型，在 20℃，溶液 pH 值为 7 的条件下，PEG-CTS 对 Zn2+的最大吸附容量是 18.2 mg/g，对 Cr6+的最大吸附容量是 14.8 mg/g。 材料重复利用性研究显示：Zn2+、Cr6+模板材料重复利用 4 次后的平 衡吸附容量分别下降了 15%和 6%，并没有太大的改变，说明 PEG-CTS 重复利用性较好。 动态吸附研究显示：1）连续输入方式下，砂柱中的重金属溶液从开 始渗出到达到或接近初始浓度，所需要的时间比 NaCl 要长。2）通过模 型计算，锌的最大吸附量下降为 0.895 mg/g，约为静态最大吸附量的 5% 左右。铬的最大吸附量下降为 6.5 mg/g，约为静态最大吸附量的 44 %左 右。 关键词：地下水，壳聚糖，聚乙二醇，吸附，锌，铬 ADSORPTION CHARACTERISTICS OF HEAVY METAL IN GROUNDWATER ADSORBED BY MODIFIED CHITOSAN ABSTRACT In China, shallow groundwater has polluted by heavy metal due to human activites. In situ groundwater remediation has been paid on attention by government and scientists. In this paper, the static and dynamic adsorption properties of heavy metal such as Zn2+, Cr6+ in groundwater was studied by cross-linked chitosan materials which were cross linked with PEG400. The result showed that under CTS: PEG=1:2, 0.1% Zn ion inprinted, the removal efficiency of Zn2+ was the highest；under CTS: PEG=1:1,1.6% Cr ion imprinted, the removal efficiency of Cr6+ was the highest. The study of infrared spectroscopy showed : Heavy metals Zn2+, Cr6+ reacted with cross-linked chitosan in different groups. The reaction between Zn2+ and PEG-CTS occurred mainly in –NH2, -OH, -O-C-O-. The reaction between Cr6+ and PEG-CTS occurred mainly in-CONH- and -O-C-O-. The study of static non-equilibrium adsorption isotherm showed: 1) PEG-CTS inprinted Zn2+ was close to the adsorption saturation after 20 h. 2) PEG-CTS inprinted Cr6+ followed a rapid adsorption to the adsorbent in 0.5 h and it was close to the adsorption saturation after 4 h. The adsorption of Cr6+ was a bit faster than the one of Zn2+. The study of static non-equilibrium adsorption isotherm showed: the adsorption of Zn2+, Cr6+ on PEG-CTS both were according to Langmuir adsorption isotherm model. Under temperature 20 ℃ and pH=7 conditions, the maximum adsorption capacity of bivalent zinc ion reached 18.2 mg per gram. The maximum adsorption capacity of chrom