电-Fenton法处理苯酚废水实验分析-农业水土工程专业论文.docxVIP

PAGE PAGE IV Abstract Electro-fenton process has become a hot point in wastewater treatment research field because of the unique advantage in treating hard degradation organic wastewater now. Using homemade electro-fenton experimental device，designing orthogonal experiment，the phenol wastewater was treated. The treating effect was evaluated synthetically by the indicators of BOD5、COD、TOC，meanwhile the biochemical quality was analysed. The intermediate products were studied by HPLC，then the electro-fenton oxidative degradation way was inferred. Combining the electro-fenton oxidation mechanism and the organic molecules structural characteristics ， the preliminary research about phenol electro-fenton oxidation degradation mechanism has done. The biochemical quality of phenol wastewater was studied by analysing the numerical value of BOD5/COD. The intermediate products in the wastewater of phenol after electro-fenton oxidation were analyzed by HPLC. The method is that taking retention time as the basis of qualitative analysis and using standard addition method to notarize the sample. The intermediate products of phenol after electro-fenton oxidation were determined and the degradation way of phenol was inferred. Under certain conditions，after electro-fenton oxidation，the BOD5 of phenol wastewater improved 45.1%，and the removal rate of COD achieved 87.3%，in the meanwhile，the TOC decreased 80.3%. At the same time，the biochemical quality of phenol wastewater has enhanced. The BOD5/COD value was up to 0.68，improving 11.3 times compare with before. Therefore ， as pretreatment before biological treatment，the electro-fenton process is feasible. It was found that in the experiment，the intermediate products of electro-fenton oxidation degradation phenol （ according to retention time order in HPLC chromatogram）：Maleic acid（tR=1.316min）、Hydroquinone（tR=1.702min）、 p-Quinone（tR=2.196min）. The electro-fenton oxidation degradation way of phenol was inferred：phenol → Hydroqu