甘油碳酸酯的反应精馏合成过程分析-工业催化专业论文.docx

华 华 中 科 技 大 学 硕 士 学 位 论 文 II II Abstract Recently, large amount of glycerol as a by-product were produced for the bio-diesel production was continuously increasing. Glycerol carbonate(GC) is one of the promising value-added glycerol derivatives due to its potential and widely used in various fields, the synthesis of glycerol carbonate was mostly studied in China and abroad. Dimethyl carbonate, which is a new-style environmental protection material, attracts broad attention from the academic world at home and abroad. CaO is a compound with low cost and can be developed as a promising catalyst for glycerol and dimethyl carbonate producing glycerol carbonate. It has great importance to construct development of society. Firstly, the HYPERLINK /kinetics/ kinetics for synthesis of glycerol carbonate was investigated with Dimethyl carbonate and glycerol over CaO catalyst. Reaction optimization study has been carried out leading to operate on conditions for achieving a high conversion and yield: Dimethyl carbonate/glycerol molar ratio: 3.58, particle size of CaO: 100 mesh, calcined temperature: 1073K, stirring rate: 1500rpm. The numerical prediction was obtained and compared with the experimental data. The result has shown a good agreement between them. Reactive distillation and extractive distillation carried out in different column was further researched in the following section of this work. The effects of the operation parameters (Dimethyl carbonate /glycerol molar ratio, reflux ratio, final temperature of tower bottom, and CaO loading) on the reactive distillation process were investigated by the systematical experiments. Under the conditions of the Dimethyl carbonate /glycerol molar ratio of 4, reflux ratio of 1, final temperature of tower bottom of 358K, CaO/glycerol molar ratio of 0.05 and tower height:400mm, the glycerol conversion and GC yield reached as high as 99%, respectively, and the concentration of calcium in the product was less 0.08 wt.%. Seeking a suit