电化学方法表征超分子凝胶的分析-分析化学专业论文.docx

华中科技大学硕士学位论 华 中 科 技 大 学 硕 士 学 位 论 文 II II 4. 采用循环伏安法研究了二茂铁在DBS的乙腈、碳酸丙烯酯、环己酮凝胶中扩散。 发现随着形成凝胶的溶剂的粘度增大，二茂铁的扩散系数降低；凝胶因子浓度增加， 凝胶三维网络结构越加致密，也在一定程度上限制了二茂铁的扩散。 关键词：电化学；组装与解组装；杂化组装；亲疏水性；扩散 PAGE IV PAGE IV ABSTRACT Self-assembly of small molecules is an important way of preparing new functional materials. Low molecular weight gelator and surfactant are good self-assembly units. Recently, the characterization of self-assembly and disassembly of supramolecular gel is a subject of increasing attention. Electrochemical method is simple, rapid and has high sensitivity and no requirement on the macro-morphology of gel. So it has a great potential on characterization of the structure of supramolecular gel. In this paper, the self-assembly and disassembly of the supramolecular gels formed by N,N-dibenzoyl-L-cystine (DBC) and the balance of hydrophobic/hydrophilic within the gemini surfactant micellar-hybridized DBC supramolecular gels were studied by electrochemical method. Then, the diffusion of micelle in gemini surfactant micellar- hybridized supramolecular gels formed by N-fluorenyl methoxycarbonyl-L-phenylalanine(Fmoc-Phe-OH) and the diffusion of ferrocene in organogels formed by 1,3:2,4-di-O-benzylidene-D-sorbitol(DBS) were investigated. The results were as follows: The reduction behavior of electrochemical probes(Europium(III) ions, potassium ferricyanide and tris( 1,10-phenanthroline)cobalt (III) perchlorate trihydrate) in gels formed by self-assembly of DBC and solution formed by disassembly of DBC were studied by differential pulse voltammetry. It was found that the reduction peak currents of electrochemical probes in gels were significantly less than in solutions. Thus the assembly and disassembly of DBC supramolecular hydrogels can be monitored by the change of the peak current of the electrochemical probes. The micellar-hybridized systems consisted of micelles formed from gemini surfactants and supramolecular gels formed by DBC. The SEM image indicated that the