环保型缓蚀剂的制备及其在金属防腐中的应用研究-应用化学专业论文.docxVIP

环保型缓蚀剂的制备及其在金属防腐中的应用研究The 环保型缓蚀剂的制备及其在金属防腐中的应用研究 The Preparation And Application Study Of The Environment·-Protecting Inhibitor In The Inhibition Of The Metal 摘 要 通过大量的实验，研究了天然环保型缓蚀荆植酸(肌醇六磷酸醒)的提取 工艺。结果发现，植酸提取的最佳酸浓度为：盐酸0．06mol／L、硫酸O．03 mol／L。 植酸的最佳萃取时间为2小时；在无机酸类萃取剂中添加了乙醇或丙酮，可大大 提高摭酸酸式盐的一次萃取率积原料利用率；提取实验中氨水、离子交换树脂 可以减少植酸中的杂质，提高产品的纯度。用稳态极化曲线、交流阻抗、塔菲 曲线及开路电位等电化学方法和SEM分别考察了分别考察了植酸和改性钠盐 两性眯唑啉(B)在模拟海水(3。5％NaCl溶液)中对A3钢的缓蚀作用和在模 拟混凝土孔隙液中对16号建筑用钢筋的缓蚀性能，得出以下结论：植酸能有 效减缓A3钢和钢筋的腐蚀，是一种优良的阳极型缓蚀剂。临界氯离子浓度与 混凝土模拟孔隙液中的pH值存在着半对数线性关系。改性咪唑啉(B)对海水 循环冷却水系统中A3钢具有良好的缓蚀性能，是一种阳极型缓蚀剂。在pH 值为9．5的碳化混凝土体系中，改性两性钠盐咪唑啉(B)具有良好的缓蚀性 能，是一种阳极缓蚀剂；在pH值为10．5的碳化混凝±模拟孔隙液中不具备缓 蚀作用。 关键词：植酸咪唑啉缓蚀作用氯离子A3钢建筑钢筋 III The The Preparation And Application Study Of The Environment—-Protecting Inhibitor In The Inhibition Of The Metal ABSTRACT 他is study inspected the abstraction way of corrosion inhibitor,弛ytic acid， which benefits the environment around US，by a lot of experiment．The result shows that the best acid concentration of Phvtic acid abstraction is that hydrochloric acid is O．06 mol／L and sulpHuric acid is 0。03mol／L．The optimal extraction time of the Ph”ic acid is two hours．The addition of the absolute alcohol and acetone will remarkably improve the rate of the Phytic acid abstraction and also improve the availability of the material．The process of the Phytic acid abstraction used ammonia water and the ion exchange resin avoid the invasion of the foreign matter． As a result，the cost of the abstraction is decreased．The experiment also studied the inhibition effect of the Ph受ic acid and the imidazoline denvate(B)on A3 steel and the concrete steel of 1 6 in simulative sea water{，3。5％NaCl solution)and simulative pore solution of the concrete by steady polarization curves，A．C impedance，Tafel curves and open potential．The result shows that the Phytic acid can remarkably inhibit the corrosion of the A3 steel and concrete steel and it is an anodic inhibitor． And the critical chloride iron coneentration and the simulative pore