《纳米材料自清洁膜研究》-毕业设计论文（学术).docVIP

二 〇 一 一 年 六 月 TiO2薄膜是众多氧化物半导体薄膜中研究最为广泛的一种材料，其表面的超亲水性和自清洁效应开辟了光催化功能薄膜材料新的研究领域。 本文以钛酸丁酯为钛源，通过溶胶-凝胶法制备了可与水以任意比例混合，并可直接涂覆使用的掺铁的TiO2溶胶。通过降解甲基橙研究掺铁量为0.5%的TiO2的光催化性；通过滴在玻璃表面的水滴的直径和水滴接触角研究掺铁量为0.5%的TiO2的亲水性；通过XRD衍射测试研究了掺铁量为0.5%的TiO2薄膜的晶相结构；通过光学电镜测试研究了掺铁前后TiO2薄膜的表面形貌特征研究结果表明：铁离子掺杂浓度为0.5％(摩尔比)的TiO2镀膜层数为3层、煅烧的时间为1.5h，温度为500℃时，所制备出的薄膜致密均匀，光滑透明且不开裂；紫外光照后，薄膜具有超亲水性和较强的光催化活性。 关键词：纳米Ti2薄膜；溶胶-凝胶法；自清洁性TiO2 film is many oxide semiconductor in film studies the most extensive a kind of material, the surface of super hydrophilic and clean effect since opened up a photocatalytic function film material new research area. In this paper, the titanium butyl acrylate acid for titanium source, through sol-gel method with water in any mixing ratio, and can be directly coating of the mixed use iron TiO2 sol. Through the degradation of methyl orange with research content is 0.5% of the iron of TiO2 photocatalysis sex; Through the drop in glass surface drops of water in the water and the diameter of the contact Angle iron content is 0.5% with research of the hydrophilic TiO2; By means of the diffraction mixed iron content is 0.5% of TiO2 film crystal phase structure; Through the scanning electron microscopy test study of the effects of TiO2 film iron and surface morphology characteristics The results show that: the iron ion doping concentration of 0.5% (Moore than ) of the mole ratio of TiO2 film coating layer 3 layer, calcining time of 1.5h and annealing temperature of 500℃, the preparation of the film even, smooth transparent and dense cracks; Ultraviolet light, the film has super hydrophilic and strong light catalytic activity. Key words: Nano TiO2 film; Sol-gel method; Self Cleaning 目 录 第一章 绪 论 1 1.1选题的目的和意义 1 1.2自清洁玻璃 1 1.2.1自清洁玻璃的概述 1 1.2.2 自清洁玻璃的分类 3 第二章 自清洁玻璃的研究方法及原理 4 2.1亲水性机理 4 2.2 TiO2的光催化原理 5 2.3纳米TiO2薄膜的制备方法 6 2.3.1溶胶-凝胶法 6 2.3.2物理气相沉积法 7 2.3.3喷雾热分解法 8 2.3.4化学气相沉积 8 3.1实验药品 10 3.2主要仪器及设备 10 3.3涂层的制备 11 3.3.1溶胶的制备 11 3.3.2基片的清洗 12 3.3.3涂覆 13 3.3.4干燥 13 3.3.5热处理 13 3.4 薄膜