碳核磁敏共振谱.pptVIP

肉桂酸正丁酯的IR、1H NMR、13C NMR * 核磁共振碳谱 13C NMR 12C is not NMR-active I = 0 however…. 13C does have spin, I = 1/2 (odd mass) Some nuclei’s nature abundance and sensitivity 1.000 0.0159 0.00104 0.834 0.066 99.9844 1.108 0.365 100 100 1H 13C 15N 19F 31P sensitivity nature abundance nuclei 13C signals are 6000 times weaker than 1H because: 1. Natural abundance of 13C is small (1.08% of all C) 2. Magnetic moment of 13C is small In order for 13C NMR to be a useful technique in structure determination.