聚乳酸改性纳米纤维素复合材料制备及性能-包装工程.PDFVIP

包装工程 第37卷第7期 28 PACKAGINGENGINEERING 2016年4月 聚乳酸/改性纳米纤维素复合材料制备及性能 俞秋燕，严灵芝，刘翔，傅天翔，张萍，高德 （浙江大学宁波理工学院，宁波315100） 摘要：目目的的 通过乙酸、高氯酸、乙酸酐等对纳米纤维素（NCC）进行乙酰化改性，再通过溶液浇铸法制 备聚乳酸/改性纳米纤维素复合材料（PLA/mNCC）。方方法法 采用紫外可见分光光度计对PLA/mNCC进 行透明性测试及透光率分析；采用FE-SEM电镜观察mNCC在复合材料中的形貌；采用动态热机械分 析仪进行动态热力学分析。结结果果 与mNCC相比，NCC在PLA基体中的分散性更好。当mNCC质量分 数小于4%时，可较均匀地分散在聚乳酸基体中，但随着mNCC含量的增加，团聚现象明显；PLA/mNCC 的储能模量随着mNCC含量的增加而提高，但是mNCC的加入对材料玻璃化转变温度的影响非常 小。结结论为改善论 PLA的加工性能提供一定的实验及理论依据。 关键词：聚乳酸；纳米纤维素；乙酰化改性；动态热力学分析 中图分类号：TB484.9 文献标识码：A 文章编号：1001-3563（2016）07-0028-05 Preparation and Performance of Poly（Lactic Acid ）/Modified Cellulose Nanocrystal Composite Materials YUQiu-yan，YANLing-zhi，LIUXiang，FUTian-xiang，ZHANGPing，GAODe （Ningbo Institute of Technology ，Zhejiang University ，Ningbo 315100 ，China） ABSTRACT ：In this paper, cellulose nanocrystal (NCC) was acetylated modified by acetic acid, perchloric acid and acetic anhydride. Then polylactic acid/modified NCC (mNCC) composite materials were prepared by solution casting. The transparency and light transmittance of composite materials were studied through UV visible spectrophotometer. The morphology of mNCC in composite materials was observed by FE-SEM electron microscopy. Dynamic thermodynamic analysis was carried out by Dynamic Mechanical Analyzer. The results showed that compared to NCC, mNCC had better dispersion in PLA matrices when the content of mNcc was less than 4%. The nano-particles tended to aggregate with further increase of mNcc content. The storage modulus of composite materials was improved with the increasing