压电陶瓷K0.5Na0.52Nb1-xSbxO3制备及性能研究.doc

合肥学院-压电陶瓷毕业论文 PAGE 第 第 PAGE \* MERGEFORMAT 1 页 共 NUMPAGES \* MERGEFORMAT 37 页 Hefei University 毕业论文 BACHELOR DISSERTATION 论文题目：压电陶瓷K0.5Na0.52Nb1-xSbxO3制备及性能研究 学位类别： 工学学士 学科专业： 无机非金属材料工程 作者姓名： xxx 导师姓名： yinqiyi 完成时间： 2014年5月 PAGE \* MERGEFORMAT IV PAGE \* MERGEFORMAT IV 压电陶瓷K0.5Na0.52Nb1-xSbxO3的制备及性能研究 摘 要 随着当今社会对环保问题的高度重视 ,人们更加重视过去压电陶瓷的研究和生产方法对环境的影响[1]。而传统的压电陶瓷，或者称含铅压电陶瓷，其大部分以锆钛酸铅（PZT）以及其系为基础的材料居多，其含量氧化铅一般60％-70％左右，有时甚至更多[2]。而氧化铅作为一种易挥发的，对人体有害的材料，其在生产、使用和废弃处理阶段，对生态环境产生很大危害，给人类成产、生活带来很多不利、不便因素[3]。其次，氧化铅的挥发性也会使材料在生产阶段化学计量比的发生偏离现象，从而使产品一致性降低，烧结过程需要密封处理，从而使其成本增加。寻找一种能媲美传统压电陶瓷综合性能的材料，而且对能源和原料生产成本低 ,开发对环境影响低，环境和谐性好的无铅压电陶瓷，用以取缔传统PZT基压电陶瓷材料 ,是如今材料学领域一项紧迫的战略性课题 在本文中，采用固相烧结法制备无铅压电陶瓷K0.5Na0.52Nb1-xSbxO3，其掺杂量x取值分别为 ，对其进行相关性能和常数测定。通过相关试验及测定，得出结论：烧结温度为1140 ℃时，掺杂水平x为0.02 ，样品的压电系数d33=111pC / N，介电常数的值εr=1200 ，机械品质因数Qm=10 ，机电耦合系数Kp=0.387，介电损耗tanδ=0.11 ，能够获得良好的压电性能和铁电性的压电陶瓷。 关键词：无铅压电陶瓷；压电效应；固相法；掺杂；铁电性能 Preparation and properties of piezoelectric ceramics K0.5Na0.52Nb1-xSbxO3 Abstract Environmental issues have attracted much attention from the society, as a result of which the the effect of research and methods of piezoceramics on environment also has arisen people’s awareness. However, traditional piezoceramics, also called lead-based piezoceramics, takes lead zirconate-titanate (PZT) and materials belonging to series of lead zirconate-titanate (PZT) as main basic material and has the main component of lead oxide which takes up about 60% to 70% or more. As well, as a volatile and poisonous substance, lead oxide can cause pollution to environment and damage to people’s life during the process of producing, using and waste treatment. Besides, the volatilness of lead oxide may cause departure of stoichiometric ratio of ceramics in the process of production, which leads to decreasing of product’s consistency and increasing of cost owing to