一种新型重金属螯合剂处理垃圾焚烧飞灰的-苏州环境保护局.DOC

PAGE \* MERGEFORMAT 4 一种新型重金属螯合剂处理垃圾焚烧 飞灰的浸出毒性安全性研究 张旭健1，王廖沙2,*王文丰2,孙昌春3 （1.苏州环境监测中心站，江苏苏州 215000；2.苏州大学，江苏苏州 215000； 3.苏州工业园区世普瑞环保科技有限公司，江苏，苏州 215000） 摘 要：用一种新型重金属螯合剂飞卡处理生活垃圾焚烧发电厂的飞灰，并对螯合后的飞灰的浸出毒性安全性进行了研究。结果表明：其浸出液浓度均满足《生活垃圾填埋场污染控制标准（GB?16889-2008）》的规定，可以进入生活垃圾填埋场。螯合后的飞灰固化物在pH≤1时，锌、镉、铅的浸出浓度都超出GB?16889-2008?，pH＞3时，所有重金属浸出毒性指标均低于GB?16889-2008，由此可见在很酸性条件下，飞灰中的固化物某些重金属会重新被浸出，产生二次污染。经28个月暴露在空气中的实验表明，期间所有重金属浸出浓度均低于(GB?16889-2008)，但是铅的浸出浓度从0.1?mg/L升到0.16?mg/L有缓慢上升趋势。因此其长期稳定性还需观察。 关键词：垃圾焚烧飞灰；重金属螯合剂；浸出毒性；安全性评定；稳定化/固化 Safety Studies of Fly Ash Leaching Toxicity from Waste Incineration by a New Type of Heavy Metal Chelating Agent ZHANG Xu-jian1，WANG Liao-sha2，WANG Wen-fen2，SUN Chang-chun3 (1.Suzhou?Environmental?Protection?Monitoring?Center ,Suzhou 215000，China; 2. Suzhou?University, Suzhou 215000，China，3.SIP SPRING Environmental Protection technology?Co.,Ltd, Suzhou 215000，China) Abstract:. A new kind of heavy metal chelator （FACAR） was used to treat the fly ash from waste incineration power plant , and the safety was studied after chelated . he results showed that the leaching liquid concentration met the requirements of “Standard for Pollution Control on the Landfill site of Municipal Solid Waste(GB?16889-2008)”, and could be accessible to the MSWI landfill . It was found that when pH was less than or equal to 1 , the leaching concentration of Zinc, cadmium and lead were beyond the requirements of GB?16889-2008 , while pH was more than 3, all heavy metal leaching toxicity indexes were lower than the requirements of GB?16889-2008. Thus it can be seen that under heavy acidic condition, some heavy metals in the fly ash solidification may be leached, causing secondary pollution. The experiments showed that in 28 months when exposed to air, all leaching concentration of heavy metals were below GB?16889-2008, but the leaching concentration of lead rose from 0.1 mg/L to 0.16 mg/L, it is a slowly rising trend. Therefore the long term stability still needs a further observat