氰化法硫代硫酸盐法硫脲法浸出某难浸银精矿比较研究张帅方夕.DOC

氰化法、硫代硫酸盐法、硫脲法浸出某难浸银精矿比较研究 张帅, 方夕辉, 陈杜娟 （江西理工大学资源与环境工程学院，江西 赣州 341000） 摘 要：对某浮选银精矿采用氰化法，硫代硫酸盐法，硫脲法进行银浸出实验，以评估三种不同浸出方法对该银精矿浸出效果．研究结果表明：在最优的工艺参数下［氰化法：碱预处理后加入铵盐，氰化钠浓度0.15?mol/L，pH值为11，液固比2:1，搅拌强度500?r/min，浸出时间为48?h；硫代硫酸盐法：氧化焙烧预处理，氨水浓度1.0?mol/L，硫酸铜浓度0.01?mol/L，硫代硫酸钠浓度0.2?mol/L，pH值为10，液固比4:1，搅拌强度500?r/min，浸出时间12?h；硫脲法：氧化焙烧和稀硫酸预浸处理，Fe3+浓度7.5×10-3?mol/L，硫脲浓度0.18?mol/L，pH=1.0，液固比为3:1，搅拌速度250?r/min，浸出时间24?h］，硫代硫酸盐方法获得的Ag浸出率为78.58?﹪，硫脲相应获得的Ag浸出率为62.43?﹪，比氰化法获得的浸出率低约3.33?﹪． 关键词：浮选银精矿；氰化法；硫代硫酸盐法；硫脲法；浸出率 Comparisons of leaching a silver ore with cyanide, thiosulfate and thiourea solutions　 Zhang Shuai Fang Xi-hui Chen Du-juan School of Resource and Environmental Engineering, Jiangxi University of Science and Technology, Ganzhou, 341000, China Abstract: The leaching experiments were carried out on samples collected from a silver concentrate with cyanide, thiosulfate and thiourea solutions so as to make sure different extraction effects these methods have，respectively. The result indicated that, under the optimal process parameters, ［Cyanide: alkali pretreatment with ammonium salt added, sodium cyanide concentration of 0.15?mol/L, pH of 11, liquid-solid rate of 2:1, mixing strength of 500?r/min, leaching time of 48?h; Thiosulfate: oxidizing roasting pretreatment, ammonia concentration of 1.0?mol/L, copper sulfate concentration of 0.01?mol/L, sodium thiosulfate concentration of 0.2?mol/L, pH of 10, liquid-solid rate of 4:1, mixing strength of 500?r/min, leaching time of 12?h; Thiourea: oxidizing roasting and then dilute sulphuric pretreatment acid pre-leaching, Fe3+ concentration of 7.5×10-3?mol/L, thiourea concentration of 0.18?mol/L, pH of 1.0, liquid-solid rate of 3:1, mixing strength of 250?r/min, leaching time of 24?h］, the leaching rate of Ag with the method of thiosulfate is 78.58?﹪, while the rate in the thiourea system is about 62.43?﹪, 3.33?﹪ lower than that in the cyanide system. Keywords: Silver concentrate; Cyanide; Thiosulfate; Thiourea; Leaching rate 1