液相沉淀热还原纳米Fe包覆Mo粉末微结构特征.PDFVIP

第 20 卷第 1 期 中国有色金属学报 2010 年 1 月 Vol.20 No.1 The Chinese Journal of Nonferrous Metals Jan. 2010 文章编号：1004-0609(2010)01-0118-07 液相沉淀−热还原纳米Fe 包覆Mo 粉末微结构特征 1, 2 1 1 1 银锐明 ，范景莲 ，刘 勋 ，张曙光 (1. 中南大学 粉末冶金国家重点实验室，长沙 410083 ； 2. 湖南工业大学 包装与材料工程学院，株洲 412008) 摘 要：采用液相沉淀−热还原法制备纳米 Fe 包覆 Mo 合金粉末，研究还原过程中的晶粒组织及微结构并进行分 析。结果表明：还原过程中，粉末晶粒平均晶粒尺寸随还原温度的升高而变小，微观应变在还原温度为 600 ℃时 最高，Mo 晶粒先于Fe 晶粒还原并长大至 1 μm 左右，Fe 晶粒粒径最终保持为 1.8 nm，并形成20 nm 左右的薄层， 沉积在 Mo 颗粒表面。 关键词：液相沉淀−热还原；Fe-Mo ；晶粒组织；微结构 中图分类号：O648.4 文献标识码：A Microstructure characteristics of nanometer Fe coated Mo powders prepared by liquid precipitation-thermal reduction method YIN Rui-ming1, 2 1 1 1 , FAN Jing-lian , LIU Xun , ZHANG Shu-guang (1. State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China; 2. College of Packaging and Material Engineering, Hunan University of Technology, Zhuzhou 412008, China) Abstract: Nanometer Fe coated Mo powders were prepared by liquid precipitation and thermal reduction. The grain structure and microstructure of materials during the reduction process were discussed. The results show that the average grain size of Fe coated Mo powders decrease with increasing reduction temperature, and the microstrain reaches the maximum at the reduction temperature of 600 ℃ . The reduction of Mo grains precedes over Fe grains and the Mo grains grow significantly. The microstructure