挥发性有机物在活性炭纤维上的吸附和电致热脱附.PDF

中国环境科学 2016,36(7) ：1981~1987 China Environmental Science 挥发性有机物在活性炭纤维上的吸附和电致热脱附 赵海洋 1,卢晗锋 1*,姜 波 2,朱秋莲 1,周 瑛 1,黄海凤 2,陈银飞 1 (1.浙江工业大学化学工程学院,催化反应 工程研究所,浙江 杭州 310014 ；2.浙江工业大学生物与环境工程学院,浙江 杭州 310014) 摘要：采用 3 种不同的活性炭纤维,考察了 VOCs 种类、VOCs 浓度以及床层温度对活性炭纤维吸附 VOCs 性能的影响,并采用电致热脱附 技术进行再生研究.结果表明, 甲苯浓度对吸附推动力影响较大,在高浓度下,可使吸附容量达到 434.8mg/g.活性炭纤维吸附甲苯受温度影响 较小,在 60℃下仍然具有 288.6mg/g 的吸附容量.电致热脱附电压越大,活性炭纤维升温速率越快,脱附效率越高,经过 100min 即可完全脱附. 经过 4 次吸脱附循环,活性炭纤维仍有较好的吸附效果,饱和吸附量能达到原有吸附量的 80%以上. 关键词：VOCs ；活性炭纤维；吸附；电致热脱附 中图分类号：X511 文献标识码：A 文章编号：1000-6923(2016)07-1981-07 1 1* Adsorption and electro-thermal desorption of VOCs on activated carbon fibers. ZHAO Hai-yang , LU Han-feng , 2 1 1 2 1 JIANG Bo , ZHU Qiu-lian , ZHOU Ying , HUANG Hai-feng , CHEN Yin-fei (1.Research Institute of Catalytic Reaction Engineering, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China ；2.College of Biological and Environmental Engineering, Zhejiang University of Technology, Hangzhou 310014, China). China Environmental Science, 2016,36(7)：1981~1987 Abstract ：The effect of adsorption conditions such as VOCs type, concentration and bed temperature on adsorption ability were investigated over the ACF. Higher concentration of VOCs resulted in higher adsorption capacity, and the adsorption capacity under 12g/m3 reached 434.8mg/g of toluene. The adsorption of toluene on ACF was less affected by temperature which adsorption capacity still remained 288.3mg/g even at 60 ℃. The higher the voltage of electro-thermal desorption, the faster the ACF heating rate, and the higher the desorption efficiency, what’s more, toluene was fully desorbed after 100minutes. In addition, ACF still had