《聚5-氯-1-苯基-1-戊炔的合成与表征》-毕业论文.DOCVIP

PAGE PAGE 7 PAGE I 池州学院 本科毕业设计（论文） 题　　目： 聚5-氯-1-苯基-1-戊炔的合成与表征 学生姓名： 学号： 070911128 系（部）： 化学与食品科学系 专业：　07应用化学 入学时间：　 　 2007　　　 年　　　　09　　 月 导师姓名：　 职称/学位： 教授/博士 导师所在单位：　 安徽省池州学院 　　　 聚5-氯-1-苯基-1-戊炔的合成与表征 摘 要 聚乙炔（PA）是一类主链含C=C的刚性共轭聚合物，由于此类聚合物具有好的热稳定性、电致发光及良好的非线性光学效应，因此在电致发光器件、非线性光学器件、传感器等领域有着重要的应用。取代聚炔兼具共轭主链的分子导线效应和侧链的功能性二个优点，表现出了广阔的应用前景。与单取代聚乙炔相比，二取代聚乙炔衍生物在发光性能、稳定性能等方面表现更突出。本研究首先采用Pd催化交叉偶联反应合成出单体芳香炔5-氯-1-苯基-1-戊炔（M），而后用WCl6和Ph4Sn催化合成出侧链带氯化物的聚5-氯-1-苯基-1-戊炔（P）。单体和聚合物已用红外光谱和核磁共振进行表征，结果表明单体芳香炔M和聚合物（P）已经合成出来。在聚合物P上接上某些功能基团，可以用作荧光传感器，从而为共轭聚合物荧光传感器的开发做了有益的探索。 关键词：功能聚炔；合成；表征；荧光传感材料； Synthesis and Characterization of Poly(5-Chloro-pent-ynyl-benzene) Abstract Polyacetylene (PA) is a kind of conjugated polymer which contains C=C bond. Due to its properties of thermo stability, light emission, fluorescence sensing and optical nonlinearity, giving the PA a wide use in the fields of electroluminescent devices, nonlinear optics, and fluorescene sensor. The substituted polyacetylene combines the molecular wire effect of conjugate chain and functionality of side chain, making it has a wide application. Among the substituted polyacetylene, disubstituted PAs are gennerally superior to their counterparts monosubstituted in performance in light emission and stability. The disubstituted PAs has a good prospect in photoelectric sensor. However, as photoelectric sensor, the disubstituted PAs are difficult to synthesize by the counterpart monomer. Generally, it’s synthesized through the stategy of postfunctinalization. We do this experiment through Pd catalyst to catalyze cross coupling reaction to synthesize the monomer of aromatic alkyne, then through the catalysis of WCl6 and Ph4Sn to synthesize the polymer, that is the category of postfunctionalization to synthesize polyacetylene metal ion sensor. The products achieved by this experiment had been made the analysi