不同温度烧制介孔碳作为直接甲醇燃料电池催化剂-IngentaConnect.PDF

物理化学学报(Wuli Huaxue Xuebao) August Acta Phys. -Chim. Sin. 2011, 27 (8), 1881-1885 1881 [Article] 不同温度烧制介孔碳作为直接甲醇燃料电池催化剂载体 徐群杰* 李金光 李巧霞 (上海电力学院能源与环境工程学院, 上海200090) 摘要: 以嵌段共聚物P123 为模板制备介孔氧化硅SBA-15, 并以此SBA-15 为模板, 以蔗糖为碳源在不同的温 度下(600-900 °C)制备介孔碳CMK-3. 采用浸渍还原法, 以硼氢化钠为还原剂, 制备介孔碳载Pt 电催化剂, 即 20% (w) Pt/CMK-3. 利用循环伏安法(CV)、计时电流法等测试电催化剂对甲醇的催化氧化性能及稳定性. 预吸 附单层CO 溶出伏安法研究测试催化剂抗CO 中毒能力. 结果表明在烧制温度为900 °C 时制备的介孔碳载Pt 催化剂具有最好的催化性能和稳定性, 而在烧制温度为700 °C 时制备的介孔碳载Pt 催化剂对CO 有较低的溶 出电位. 关键词: 介孔碳; 甲醇; Pt; CO 溶出 中图分类号: O643 Preparation of Mesoporous Carbon at Different Temperatures as a Catalyst Support for Direct Methanol Fuel Cells XU Qun-Jie* LI Jin-Guang LI Qiao-Xia (Department of Thermal Power and Environmental Engineering, Shanghai University of Electric Power, Shanghai 200090, P. R.China) Abstract: Using mesoporous SiO (SBA-15) as templates and sugar as a carbon precursor, mesoporous 2 carbon (CMK-3) was prepared at different temperatures (600-900 ° C). 20% (w) Pt/CMK-3 was then prepared by impregnation reduction with sodium borohydride as a reductant. Cyclic voltammetry (CV) and chronoamperometry were applied to study the catalytic performance and stability toward methanol oxidation for the as-prepared catalyst. CO striping voltammetry was used to determine its anti-poisoning capability toward CO. The results show that the Pt/CMK-3 prepared at 900 ° C had the best cata