贝壳类新型钙基脱硫剂的试验研究-环境科学学报.PDF

第 23 卷第 5 期 环 　境 　科 　学 　学 　报 Vol . 23 ,No . 5 2003 年 9 月 ACTA SCIENTIAE CIRCUMSTANTIAE Sep . ,2003 ( ) 文章编号 2003 　　　中图分类号 :X506 　　　文献标识码 :A 贝壳类新型钙基脱硫剂的试验研究 ( 山东大学能源与动力工程学院 ,热能工程研究所 ,济南 　250061) 张 　雷 ,路春美 ,程世庆　 摘要 :将贝壳用于流化床进行燃烧脱硫试验研究 ,并与一种优质石灰石比较. 结果表明, 贝壳具有比石灰石更高的脱硫效率 和钙利用率 ;并且具有更好的高温硫化反应活性 , 贝壳的最佳脱硫温度比石灰石约高 100 ℃. 利用压汞仪对试验样品进行微 μ μ 观结构测定 ,煅烧后贝壳的微孔直径主要集中在 02 —50 m 之间 ,而石灰石的微孔直径主要集中在 0005 —0142 m 之间 , 贝壳表现出较好的微观孔结构特性. 研究表明,贝壳是一种固硫性能较好的新型钙基脱硫剂. 关键词 :贝壳 ;石灰石 ;流化床燃烧 ;钙基脱硫剂 Experimental study on the ne wtype calciumbased sorbent shell ( ) ZHANG Lei ,LU Chunmei ,CHENG Shiqing 　 Institute of Energy and Power Engineering , Shandong University , Jinan 　250061 Abstract :Shell was used in the study of fluidizedbed combustion desulfurization experiment , which was compared with one kind of good lime stone The results show that shell has higher desulfurization efficiency and calcium utilization ratio than limestone , and furthermore , it has bet ter hightemperaturereaction activity , the optimum desulfurization temperature of shell is about 100 ℃higher than that of limestone . Micro scopic structure of the test samples was measured by mercury porosimeter . Pore diameter of the calcined shell mainly focuses the range of 02 μ μ to 50 m , while that of the calcined limestone is mainly between 0 . 005 and 0142 m Shell represents better microstructural characteristic of inner pore . The results show that shell is one kind of newtype sorbent with better desulfurization performance t