超微二氧化硅的超声制备及影响因素分析-JournalofNortheastern.PDF

第29 卷第5期 东 北 大 学 学 报 ( 自 然 科 学 版 ) Vol129,No.5 2008 年 5 月 Journal of Northeastern niversity( Natural Science) May 2 0 08 申晓毅, 刘 岩, 翟玉春, 顾惠敏 ( , 110004) : - ,, ; XRD, SEM IR , , # ,, # , , , , # : - ;; ;; : TQ 127. 2 : A : 1005-3026( 2008) 05-0705-04 Ultrasonic Preparation of Ultrafine Silica and Analysis of Influencing Factors SHEN X iao-y i, L I U Yan, ZHAI Yu-chun, G U H ui-min ( School of materials Metallurgy, Northeastern niversity, Shenyang 110004, China. Correspondent: LI Yan, E-mail: liuy @ smm. neu. edu. cn) Abstract: T he ultrafine silica powder was prepared ultrasonically using sol-gel method in 2- propanol-H O-NH system, where the ammonia acts as the catalyst during reaction. The ultrafine 2 3 silica powder sample was characterized by SEM, XRD and IR, and the results indicated that the SiO2 particles thus prepared are amorphous in regularly spheric shape with uniform size and contain lots of hydroxides. The influences of ultrasonic power, reaction temperature, mole mixture ratio of reactants and concentration of ammonia solution on sample. s morphology and particle size were studied through some single-factor experiments, and the results revealed that the ultrasonic power affects particle size greatest with the mole mixture ratio of reactants as the next. Besides them, the influence of the concentration of ammonia solution is also considerable. Key words: sol-gel method; ultrasonic technics; ultrafine silica; amorphism; ultrasonic preparation SiO , TEOS SiO , 2 2