壳聚糖季氨化聚乙烯醇离子交换膜制备表征.docVIP

基金项目：福州大学国家级大学生创新创业训练计划项目(201610386014)。 作者简介：孟枫舒(1997-), 男，在读本科生。 联系人：江献财(1985-)，男，讲师，主要从事聚乙烯醇和壳聚糖复合材料制备工作。Email: jiangxc@。 壳聚糖/季氨化聚乙烯醇离子交换膜制备表征 孟枫舒，张宏翔，陈乾，庄佳瑗，石华峰，孙玉俊，江献财*\ （福州大学，石油化工学院，福建 福州 350116） 指导教师：江献财 职称：副教授 摘要: 采用氯化铝水溶液为壳聚糖(CS)的溶剂，通过季氨化改性得到季氨化的PVA (QPVA)，并通过溶液复合制备得到了QPVA/CS复合薄膜，并研究了QPVA/CS复合薄膜作为碱性燃料电池隔膜的性能。通过傅里叶变换红外光谱、X射线衍射分析和力学性能测试研究氯化铝和甘油对QPVA/CS复合薄膜的性能的影响。通过吸水率研究了QPVA/CS复合薄膜的吸水性能，并对复合薄膜的离子传导率进行了测定。研究结果表明，同时加入氯化铝和甘油改性时，制备的QPVA/CS复合薄膜的性能较好，其拉伸强度为23 (± 0.67) MPa，断裂伸长率为235 (± 2.85)%，离子传导率为2.028×10-2 S cm-1。 关键词：壳聚糖，聚乙烯醇，阴离子交换膜，六水合氯化铝，甘油 Preparation and characterization of quaternized poly(vinyl alcohol)/chitosan composite anion exchange membrane Fengshu Meng, Hongxiang Zhang, Qian Chen, Jiayuan Zhuang, Huafeng Shi, Yujun Sun, Xiancai Jiang （School of chemical engineering, Fuzhou University, Fuzhou, Fujian 350116, China） Abstract: In this paper AlCl3·6H2O aqueous solution was used as the solvent for chitosan, and quaternized poly(vinyl alcohol)/CS (QPVA/CS) membrane was prepared by solution casting. The effect of AlCl3·6H2O on the the hydrogen bonding interaction, crystalline properties and mechanical properties was studied by fourier transformed infrared spectra, X-ray diffraction measurement and tensile testing, respectively. The ion conductivity of QPVA/CS membrane was studied by AC impedance method. The results showed that both AlCl3·6H2O and glycerol could form interaction with QPVA/CS. With the addition of AlCl3·6H2O and glycerol, the crystallinity of QPVA/CS membrane decreased and the flexibility of QPVA/CS membrane increased. With the addition of AlCl3·6H2O and glycerol, the elongation at break of QPVA/CS could reach to 235 ± 2.85% and the ion conductivity could reach to 2.028×10-2 S cm-1. The results of this paper provided a new way for the preparation of high performance QPVA/CS composite anion exchange membrane. Keywords: chitosan, poly(vinyl alcohol), anion exchange membrane, AlCl3·6H2O, glycerol 燃料电池隔膜是燃料电池中的关键部件[1]。近年来通过环境友好、成本低廉和电导率高的高分子膜制备燃