利用核磁共振技术研究热处理中密度纤维板的吸水性-安徽农业大学学报.PDF

安徽农业大学学报, 2018, 45(4): 645-649 Journal of Anhui Agricultural University [DOI] 10.13610/ki.1672-352x035 网络出版时间：2018/8/27 17:20:20 [URL] /kcms/detail/34.1162.S1807.070.html 利用核磁共振技术研究热处理中密度纤维板的吸水性 * 陶德亨，李新宇，刘文静 ，郎 真 ( 内蒙古农业大学材料科学与艺术设计学院，呼和浩特 010018) 摘 要：基于时域核磁共振技术，对3 个热处理温度（120、170 和220℃）下MDF （中密度纤维板）的吸水 性进行了研究，并利用X 射线衍射技术，辅助揭示不同样品吸水性差异的机理。结果表明，170℃处理MDF 吸水 过程中吸水率、自由水和结合水含量最低；220℃热处理 MDF 的纤维素结晶区被破坏，原有的空隙结构被改变， 吸水率、自由水和结合水含量最高。 关键词：中密度纤维板；吸水；时域核磁共振；横向弛豫时间 中图分类号：TS653.6 文献标识码：A 文章编号：1672352X (2018)04064505 Water adsorption of heat-treatment medium density fiberboard studied by TD-NMR technique TAO Deheng, LI Xinyu, LIU Wenjing, LANG Zhen (College of Material Science and Art Design, Inner Mongolia Agricultural University, Hohhot 010018) Abstract: In this study, water absorption of MDF (medium density fiberboard) treated with high tempera- tures (120 ℃, 170℃ and 220 ℃) was studied using the time-domain nuclear magnetic resonance technique. The x-ray diffraction technique was used to reveal the effect mechanism of heat-treatment on the water absorption, and the results showed that the contents of free water and bound water of MDF treated at 170 ℃ were the lowest, which meant 170 ℃ was the ideal heat-temperature in this experiment. In addition, the crystal and pore structures of MDF treated at 220℃ were changed, and their contents of free water and bound water were the highest. Key words: MDF; water adsorption; TD-NMR; T2 中密度纤维板（MDF ）凭借良好的物理、力学、 Çavdar 等[4]将 220 ℃热油处理 MDF 和未处理 MDF 装饰和加工性能，广泛用于家具制造、室内装修和 对比研究发现，热油处理降低了 MDF 的吸水率、 建筑材料等领域。但由于 MDF 是一种亲水性材料， 吸水厚度膨胀率、静曲强度和弹性模量。