LC-ESIMS分析食品中微量苏丹红~.PDFVIP

24 4 Vol. 24 No. 4 2005 7 FENXI CESHI XUEBAO( Journal of Instrum ntal Analysis) 28~ 31 研究简报 LC- ESI/ MS Ñ~ Ô 喻凌寒, 杨运云, 闫世平, 陈江韩, 李光宪, 牟德海, 蔡大川 ( , 510070) : LC- ESI/ MS 4 , A il nt C18( 15 cm @ 2. 1mm, 3 m) , - 0. 5% ( 72 B 28) g L , 3 , 4 ( LOD) ( LOQ) ng/ g 0. 2 / 86% ~ 98% , 8min, Lg g : ; ; ; : O657. 63; TS 202. 3 : A : 1004- 4957( 2005) 04- 0028- 04 D t rmination of Trac Sudan Ñ- Ôin Food b HPLC- ESI/ MS y YU Lin _han, YANG Yun_ un, YAN Shi_ in , CHEN Jian _han, LI Guan _xian, MU D _hai, CAI Da_chuan g y p g g g ( Guangdong K y Laboratory of Ch mical Em rg ncy T st, China National Analytical C nt r, Guangzhou, Guangzhou, 510070, China) Abstract: A ra id and r liabl m thod for th d t rmination of trac Sudan Ñ, Ò, Ó and Ô in food p stuffs b r v rs d_ has li uid chromato ra h - ESI/ MSD was r s nt d. Th Sudan d s w r xtract d y p q g p y p y with ac tonitril and th cl an_up proc dur was not r quir d. An Agil nt C18( 15 cm@ 2. 1 mm) column with ac tonitril - 0. 5% ac tic acid mixtur as th mobil phas was us d und r isocratic conditions( 72 B 28 b volum ) . Th mass s ctra was ac uir d in ositiv ion mod . For ach com ound, thr fra m nt y p q p p g ions w r s l ct d as qualitativ ions to obtain high s l ctivity, and th most abundant fragm nt of ach com- pound w