北京大学电分析课件液液界面电化学及电分析化稳学简介elect7.pptVIP

目前国际上液/液界面电化学研究 存在的主要问题 1. 界面结构未知! MVN模型和混合溶剂层模 型(GS) 2. 可供选择作为有机相的有机溶剂数目有限 3. 没有很好的获取转移反应动力学的实验手段 4. iR(i-电流，R-电阻，iR降是由于溶液中电阻 所引起的干扰)降及充电电流较常规电化学更 加严重 How to solve these Problems Microelectrodes: Solid and Nano- and Micropipettes + Scanning Electrochemical Microscopy, SECM Electrochemistry at L/L Interfaces Artificial Membrane/ Electrolyte Interfaces BLM Artificial Membrane and Biosensors Modified L/L Interfaces Microelectrodes Nano- and Micropipettes SECM The SEM diagrams of Nano- and Micropipettes Micropipettes Nanopipettes Micropipettes Theta (?)Micropipette The SEM diagrams of Nano- and Micropipettes Micropipettes Nanopipettes 我们group可以制备内径从几个nm到 十几个?m的玻璃纳、微米管 Aqueous Phase Organic Phase Aqueous Phase Organic Phase Asymmetric Diffusion Field TBATPB as supporting electrolyte in DCE TBATPBCl as supporting electrolyte in DCE BTPPATPB as supporting electrolyte in DCE Micropipette as a tool to determine the ionic species limiting the potential window at L/L Interfaces TBATPB (Tetrabutyalammonium tetraphenylborate) TBATPBCl(tetrabutyl- ammonium tetrakis[4-chloro phenyl]borate) BTPPATPB (Bis[triphosphor- anylidene]ammonium tetraphenyl- borate) 1,2-dichloroethane (DCE) Ag/AgCl/0.01MTBACl/0.25mMDB18C6+0.01MTBATPBCl//0.01MKCl/AgCl/Ag Identify the different mechanisms ACT TOC TIC TID w o w o w o w o Identify of different mechanisms of facilitated ion transfers Idisk =4nFaDC Ipip =3.35?nFaDC Why Ipip is about 2.63 times bigger than Idisk ? Silanization plays very important role here! Anal.Chem., 1998, 70,p3155-3161 3.4E-9 Nanometer-sized L/L Interface 纳米管 Nanopipet Aqueous Phase Nano-ITIES ko from 0.1cm/s to 10cm/s A 54nm radius B 5nm radius J.Am.Chem.Soc., 1997, 119, 8103 K+(w) + DB18C6(DCE) = [K+DB18C6](DCE) * 液/液界面电化学及电 分析化学简介 邵元华, 教授 College of Chemistry and Molecular Engineering Peking University 二00二年十一月 1.液/液界面电化学的发展历史 2.液/液界面电化学的基本原理 3.液/液界面电化学的主要研究方法 及仪器设备 4.液/液界面电化学的现状 5.液/液界面电化学的未来展望 主要内容 参考书和文献： 1. 液/液界面电化学， P.Van