双连续相导热复合材料成型工艺和性能的研究-材料科学与工程专业论文.docxVIP

且易成型加工，内部缺陷较少，热导率较高，当LG含量为65％时，材料 且易成型加工，内部缺陷较少，热导率较高，当LG含量为65％时，材料 的热导率为1．964 W·m·K)～；当LG添加量为60％，HDPE／PA6的比例为 10／8、9／9、8／10时HDPE．PA6二者能够形成双连续相，当HDPE／PA6配 比为8／10时，材料热导率达2．463 W·(m·K)～。选取HDPE／PA6配比为8／10 体系，添加60％的LG、3％的CF，材料拉伸强度和弯曲强度分别为42．68 MPa和66．00 MPa，冲击韧性十分优良，HDT达163．4C，比纯HDPE高 139．94％；热导率提升到2．737 W·(m·K)～，比纯HDPE高7．92倍。 3。实验证明，在双连续相体系中引入交联结构能够提升材料的整体 性能：相比未交联体系，交联．双连续相HDPE／PA6／LG体系弹性模量为 1594．77 MPa，增加了46。63％，拉伸强度为37．20 MPa，提升了3．56％， 弯曲强度为67．46 MPa，提升了7．40％；交联材料的冲击韧性也十分优良 为5．23 kJ／m2，材料耐热性较好HDT为129．0C，交联材料的热导率为2．634 W-(m·K)～。 总之，通过交联、双连续相形成、交联／双连续相协同作用及添加多 种导热填料的方法，能够在保证高填充时复合材料导热性能的同时，最大 程度的提升材料的力学性能，最终得到交联．双连续相导热复合材料 HDPE／PA6／LG／CF的弹性模量为2472．55 MPa，拉伸强度为45．73 MPa， 弯曲强度为72．75 MPa，断裂伸长率为1．75％，冲击强度为3．40 kJ／m2，热 变形温度为176．3C，热导为率3．214 W·(m·K)～，满足了LED散热的市场 i昏—扭 商．水。 关键词：交联，双连续相，力学性能，导热，复合材料 II 万方数据 ABSTRACTMoULDING ABSTRACT MoULDING AND PROPERTIES oF CO．CONTINUOUS PHASE THERMAL CONDUCTIVE COMPOSITES ABSTRACT In this article，the extrude-prilling process and the injection moulding process were used to prepare the crosslinking，the CO—continuous phase，and the crosslinking／co—continuous phase thermal conductive composites，which had high thermal conductivity and good mechanical properties．The effects of crosslinking and the formation of co—continuous phase on all of the properties of the composites were mainly researched：(1)The effects of the graft—crosslinking，particle size of MgO，the content of silane coupling agent modifying MgO，the content of MgO and the addition of flow additives on the properties of the thermal conductive composites of the crosslinking high density polyethylene(HDPE)／MgO were researched．(2)The effects of the characterization of co-continuous phase，the formation of co-continuous phase， the amount of matrix resins，the content of the flake graphite(LG)，the ratio of HDPE／nylon 6(PA6)，and the addition of carbon fiber(CF)on the properties of CO—continuous phase HDPE／PA6／LG thermal conductive composites were studied．(3)The synergy of the two means(crossl