新型碳纤维基rgopvd的f导电复合膜的制三备及性能研究.docx

新型碳纤维基RGO／FVDF导电复合膜的制备及性能研究Study 新型碳纤维基RGO／FVDF导电复合膜的制备及性能研究 Study of preparation and performance of a novel carbon fiber based RGO／PVDF conductive composite membrane Abstract Membrane bioreactor(MBR)iS an efficient wastewater treatment system which combines membrane separation technology with biological treatment，and has been widely used in the world for its high solid-liquid separation efficiency，good quality of effluent water and stable operation．However，the high energy cost，frequent cleaning after fouling and replacement of membrane etc．，which hinder its further application．Recent studies indicate membrane fouling Can be mitigated effectively when conducting an small electric field on the conductive cathode membranes，which not only reduce energy consumption,but also make the membrane electrode reusable．And it can be used as cathode to couple microbial fuel cell (MFC)to treat wastewater and generate electricity at the same time，which solve the effluent quality problem caused by anaerobic conditions and limited residence time in MFC，meeting the emission standards，and generated electricity is used to supply electric field instead of external power to mitigate membrane fouling．But problems in preparing conductive membranes such as poor conductivity，high production cost，and shedding of the conductive component exist．For preparing novel，low cost conductive membrane with good performance，the following work has been carried out in this paper： Preparation and characterization of conductive membranes：the GO／PVDF composite membrane is prepared by phase-inversion method using the conductive carbon fiber cloth as substrate and polyvinylidene fluoride(PVDF)doped with graphene oxide(GO)as the casting solution．The formed GO／PVDF composite membrane is heat-treated in hydroiodic acid(HI) solution to reduce graphene oxide to its reduced form，forming the reduced graphene oxide (RGO)／PVDF composite membrane．From the characterization conductivity test，it is proved that part of GO is