杂原子mcm-48催化剂对的的制备及其催化性能研究.docxVIP

Cu．Ni／MCM．48催化CH30H与C02直接合成DMC及工艺条件优化 Cu．Ni／MCM．48催化CH30H与C02直接合成DMC及工艺条件优化 Preparation of heteroatomic MCM一48 catalyst and the research of catalytic performance Abstract The synthesis of dimethyl carbonate by methanol and carbon dioxide IS all attracting route，which addresses the goes of carbon dioxide and the problemof methanol overcapacity． Ia3d cubic structure MCM-48 with two independent and inter-connected higher passable channels has promising prospect in catalysts．but is catalytic inert．111e author combined the the advantages of the reaction system and the material，applied the MCM一48 doped with copper or／and nickel as catalysts of the direct synthesis dimethyl carbonate by methanol and carbon dioxide． MCM．48 was synthesized successfully by hydrothermal synthesis in the presence of fluoride ion F‘which can enhance hydrothermal stability of mesoporous silica，the effects of template agent，water and the crystallization temperature on molecular sieve structure was scrutinized．The samples were characterized by X-ray diffiaction(XRD)，Scanning Electron Microscope(SEM)，Transmission Electron Microscope(TEM)，N2 adsorption-desorption measurements，the results manifested that the optimal synthetic conditions of molecular sieve MCM一48 were as fcIllowed：n(Si)：n(CTAB)2l：O．20，n(Si)：n(H20)2l：70，T(crystallization temperature)=1 50℃． At the optimal synthetic conditions，copper or／and nickel was／were incorporated into／onto MCM一48 by direct hydrothermal synthesis and traditional impregnation，the effects of metal contents．single／double metal，metal molar ratio molecular sieve structure was scrutinized．The samples were characterized by X—ray diffraction(XRD)，Inductively Coupled Plasma Atomic Emission Spectrum(ICP-AES)，Infrared Spectroscopy(IR)，N2 adsorption- desorption measurements．the results manifested that the MCM一48 retained its orderly three．dimensional structure when doped with certain metal。The most contents of metal call reach n(Si)：n(Cu)=l：0．025，n(Si)：n(Ni)=1：0．030，n(Si)：n(