电纺法制备过渡金属氧化物纳米碳纤维复合材料及其电化学性能-材料工程专业论文.pdf.docxVIP

摘要关键词：超级电容器；静电纺丝；金属氧化物 摘要 关键词：超级电容器；静电纺丝；金属氧化物 II 万方数据 AbstractAbstract Abstract Abstract Compared with traditional electric energy-storage devices，such as capacitors and batteries，supercapacitors attracted a great deal of attention for its high specific capacitance，quick charge-discharge rate，perfect cycle performance and friendliness tO the environment，making it possible to bridge the gap between power density with energy density．Materials used for supercapacitors mainly include carbon materials， transition metal oxides and conducting polymer．Transition metal oxides own much higher theoretical specific capacitance than carbon materials for their different mechanism of charge storage，but poor conductivity and low mass．ratio active material which undergoes redox reaction and stores energy make lots of performance loss．Fabricating composites that combine transition metal oxides with carbon material is an effective method tO achieve good electrochemical performance In this thesis，good-morphology composites of C0304／C nanofibers，Mn02／C nanofibers，and NiC0204／C nanofibers were successfully fabricated by electrostatic spinning，hydrothermal method and oil bath method，whose electrochemical performances were tested and analyzed． C0304／C nanofibers composite in which the C0304 nanoparticles insert into the C nanofibers randomly was successfully fabricated by electrostatic spinning， possessing good electrochemical performance．The specific capacitance of this material was 1 284 F／g when the charge-discharge current density was 0．5 A／g，and the specific capacitance still maintain 590 F／g when the current density increased 1 20 times tO 60 A／g，indicating the good rate capability．The coulombic efficiency calculated by the ratio of discharge time with charge time Was greater than 98％when the current density was above 8 A／g，indicating the high efficiency of charge and discharge．The cycle performance was tested at the current density of 20 A／g，showing that the specific capacitance ma