蛋白质共轭氧化锌纳米复合物和二维薄膜的制备及功能研究-有机化学专业论文.pdf.docxVIP

AB AB STRACT Zinc oxide nano-materials(ZnO)have wide applications in many fields because of its small particle size，large specific surface area,more active sites，especially in photocatalytic and antibacterial fields．In this thesis，biomimetic synthesis technology was applied to synthesize protein conjugated zinc oxide nanocomposites under facile conditions by using zein as template，which is cheap and easy to get．The morphology Was observed by High·resolution transmission electron microscopy and Scanning electron microscope．The composites and content of the llano—materials were analyzed by XRD，FTIR，and TG-DSC Taking into account lacks of nano-materials at the recovery and recycling uses，we farther improved protein conjugated zinc oxide nano-eomposites by endowing magnetic properties to it or fabricating it into 2-D thin films．Finally，the photocatalytic activity and biological activities were also assessed respectively．This thesis contains the following three parts (1)The nano-composites with well uniform and dispersity were synthesized．The antibacterial results by disk diffusion method showed that the synthetic nano—composites could significantly inhibite the growth of Escherichia coli and Staphylococcus and the inhibitory effects exhibited dosage-dependent mode．At the same time the photocatalytic results showed that Zein-ZnO had good activity and stability at the degradation of methyl orange under the illumination of 600 w high pressure mercury lamp． (2)The ion dsorption method was developed to synthesize magnetic protein conjugated zinc oxide nano-composites under facile conditions．The antibacterial results by disk diffusion method showed that magnetic nano-composites still had significantly antimicrobial activity against Escherichia coli and Staphylococcus aureus and the inhibitory effects exhibited dosage-dependent mode．The degradation of magnetic Zein-ZnO methyl orange got to 56．84％in 15 rain and 68．77％in 120 miIL respectively． However，the photocatalytic stabili