电纺pvdf基凝胶态聚合物电解质的制备与研究-测试计量技术及仪器专业论文.pdf.docxVIP

AbstractAbstract Abstract Abstract The gel polymer electrolyte is a significant electrolyte between the dry solid polymer electrolyte and the liquid electrolyte．It not only has favorable ionic conductivity at room temperature，but also Can solve some security problems such as leakage，flammable and combustible to a certain degree．As a result，it has received widespread attention．Through the electrostatic spinning technique，polymer fiber membranes are prepared with high porosity and homogenerous morphology,and combined with organic electrolyte to form the gel polymer electrolyte，exhibiting excellent electrochemical properties．So in the field of lithium-ion battery,electrospun fiber membrane has remarkable development prospect．Because of high dielectric constant and low glass transition temperature，Poly(vinylidene fluoride)(PVDF)has become one of the most commonly used materials to prepare polymer electrolyte．But due to the high crystallinity and hydrophobicity,the porosity,electrolyte uptake and electrochemical properties of electrospun PVDF fiber membranes still need to be further improved．Firstly,in this paper the polymethyl methacrylate(PMMA)polymer or inorganic Si02 nanoparticles is added into the PVDF spinning precursor solution． After electrospinning the binary compound fiber membranes，the physical properties and electrochemical properties of PVDF polymer fiber membranes are all improved． Secondly,this paper presents four methods to electrospin the ternary composite fiber membranes including PVDF,PMMA and Si02．It is found that the fiber membranes of blend electrospinning show the best performance．Thirdly,for developing the hydrophilic，different contents of glyceryl alcohol and polyethylene glycol(PEG) 20000 are introduced into the PVDF,respectively．The test results eluciate that glyceryl alcohol and PEG 20000 call reduce the crystallinity and enhance the electrochemical properties of PVDF fiber membranes．Finally,this paper puts forward a design about