聚苯胺基超级电容器电极材料的制备及电容性能研究-材料科学与工程专业论文.docxVIP

优秀毕业论文 精品参考文献资料 北京化工大学硕士学位论文形成 北京化工大学硕士学位论文 形成V-型通道。和PANI@CNFs复合电极材料相比，PANI@NPCNFs复 合材料的阻抗更小，比容量更高。和纯PANI相比，PANI@NPCNFs的初 始容量稍低，但是倍率性z日1匕l--,更好，电流密度从0．5A g。1升到20A gJ比容量 保持率为79％。 (3)改变苯胺单体的浓度，观察聚苯胺包覆层的形貌变化并分析 PANI@NPCNFs复合材料的电化学性能变化，当聚合溶液中苯胺单体的含 量为15mmol时，聚合得到的复合材料PANI@NPCNFs一15表现出最佳的 电化学性能，在0．5A g一电流密度下的放电比容量高达436．8F g～，且在 10A g。1的电流密度下，1000次循环后比容量仅衰减了4％。 关键词：超级电容器，聚苯胺，纳米纤维，氮／磷共掺杂，化学聚合法 万方数据 ABSTRACT———————————————--—————————————————————————__—--●_—-—————’———————_——^—●-’H●-●_——————————————————--———-———_-_—_—_——_-__——— ABSTRACT ———————————————--—————————————————————————__—--●_—-—————’———————_——^—●-’H●-●_——————————————————--———-———_-_—_—_——_-__———一 PREPARATION AND ELECTRoCHEMICAL CAPACITIVE CHARACTEIUSTIC oF PoLYANILINE．BASED SUPERCAPACITOR ELECTRODE M鼹ERIALS Abstract Polyaniline (PANI)have attracted considerable attention as supercapacitor electrode material，due to excellent pseudo—capacitive properties，tunable conductivity and environmental stability，easy synthesis， and low cost．In particular,PANI nanofibers attract more and more interest because of their more active surface area and higher porosity,which can form 3D conductive network and then reduce the electrode resistance．On the other hand，polyaniline／carbon composites have also aroused the concern of the researchers because the composites not only achieve high specific capacitance but also ke印excellent cycle stability． HoweveL the morphology control and uniform dispersion of PANI nanostructure have always been the challenge for developing the poyaniline@!carbon composites．This paper focuses on the controllable preparation of PANI nanofibers and their composing with different carbon substrate for the development of high capacitive supercapacitor electrode materials． (1)The chemical oxidation polymerization was used to prepare PANI nanofibers．The PANI prepared in 1 mol L‘1 H3P04 system showed the 万方数据 万方数据 万方数据 北京化工大学硕士学位论文morphology 北京化工大学硕士学位论文 morphology of wel l—ordered nanofibers and the best cap