聚苯胺纳米复合材料的制备及其微波吸收和电化学性能研究-应用化学专业论文.docxVIP

优秀毕业论文 精品参考文献资料 AbstractAb Abstract Ab Stract Polyaniline(PANI) as a typical conducting polymer，has been applied in microwaVe abso叩tion，electromagIletic waVe sheilding and supercapacitor electrodes for its ease of synthesis，excellent physical and chemical perforrnance as well as enViromnental stability．HoweVer，it still belongs to a class of semiconductors even after doped with protonic acids，the drawback of low electric conductivity restricts its applications．In order to oVercome this problem，PANI is usually combined with some other nanomaterials with high electric conductiVity such as carbon nanotubes or gr印hene nanosheets．In addition，nanocomposites of PANI combined with magnetic nanomaterials are expected to haVe good electric as well as magnetic properties． Carbon quantum dots(CDs)，as a new kind of carbon-based nanomaterials，refer to tiny carbon nanopanicles in size of sub-1 0 nm，and composed by印2-hyb“dized carbon atoms．In recent years，CDs haVe attracted more and more attentions in the area of cell imaging，biosensor and photocatalysis applications，due to their low cost， ease to synthesize， excellent nourescence and Very low cytotoxicity． More imponantly，it has been reponed that CDs are both good electron donors and eIectron receptors．In this thesis，CDs were prepared through one-pot pyrolysis method by using konj ac flour aLs a new carbon resource． Two temary composites of PANI／fe盯0cene／CDs and PANI／CoS／CDs were synthesized by in situ polymerizations respectiVely．The mo叩hology，microstmcture，capacitance and microwave abso印tion propenies ofboth tema叫composites haVe been studied．In particular，the innuence of an applied magIletic field(MF)on mo叩hology，microstmcture，capacitance and microwaVe abso叩tion propenies of PANI／CoS／CDs has been inVestigated．The main works are included f-0llows： 1．CDs with a size distribution of 1—2 nm were prepared by using konj ac nour as a carbon source．A tema叫composite of PANI／f-errocene／CDs was synthesized by in situ polymerization of anil