电化学合成取向聚噻吩衍生物薄膜-材料科学与工程专业论文.pdf.docxVIP

HDPE薄膜表面发生取向。经器件电导率测试发现，在垂直于薄膜拉伸方 HDPE薄膜表面发生取向。经器件电导率测试发现，在垂直于薄膜拉伸方 向，PEDOT电导率为5．2 S-cm～，而平行于薄膜拉伸方向其电导率仅有0．28 S．cm～。两方向电导率的较大差异证明利用电化学附生方法获得取向导电 聚合物是一种有效方法。 关键词：导电聚合物，电化学沉积，取向，聚3一己基噻吩，聚3，4-乙撑二 氧噻吩，电导率 U 万方数据 ABSTRACTELECTRoCHEMICAL ABSTRACT ELECTRoCHEMICAL PoLYMERIZATION oF oIUENTED FILMS OF POLYTHIoPHENE DERIVATIVES ABSTRACT Conducting polymers have been extensively studied and have great prospects in application since they were discovered．But their electrical conductivity are far less than of metals’．So the strategies for improving the electrical conductivity and performance of organic thin film electronic devices are diverse．Research is especially focused on synthesizing new active materials，device interface control，device structure modification and film morphology regulation．We combine electropolymerization with epitaxial to prepare oriented polythiophene derivatives and improve charge mobility in this experiment． 1．The synthesis and characterization of oriented poly(3一hexylthiophene) (P3HT)film． We obtained anisotropic P3 HT films from cyclic voltammetry on oriented isotactic polypropylene(iPP)films successfully．The orientation of P3HT was proved by methods of polarized optical micrographs(POM)， polarized FTIR spectrometer and polarized raman and SO on．We also proved III 万方数据 北京化工大学硕士学位论文that 北京化工大学硕士学位论文 that highly ordered P3HT lamellae existed in edge—on orientation on iPP film and has some angle with respect to iPP molecular chain．These P3HT films exhibit anisotropic charge mobility between the parallel and vertical to the drawing direction of films．We provide an effective method for improving the performance of the device． 2．The synthesis and characterization of oriented poly(3，4一ethylenedioxythiophene)(PEDOT)film． We obtained anisotropic PEDOT films by cyclic voltammetry on oriented high density polyethylene(HDPE)films successfully．The morphology of films were characterized by scanning electron microscope(SEM)．We proved the orientation of PEDOT on HDPE f