基于超临界流体法的聚合物多孔材料制备-材料加工工程专业论文.docxVIP

优秀毕业论文 精品参考文献资料 II AbsractAbstract Absract Abstract Porous polyIners haVe receiVed an iIlcreaSed leVel ofresearch nerest because of their potentialto me略e the propenies of both porous materials and polyIners，suCh as lligh surf．ace area，easy process abihty and Various掣nthetiC routes．T}aditional methods to prepare porous polymer such aS ph2Lse separation metllod 11eed a IIlass of o唱a11ic solVents which will lead to serious erⅣ的mnental poulltion．Supercritical fluid is widely used iIl the synthesis and process of polymers as aIl ane加ative s01vent f．0r its exceUent p11ysical and che血cal properties． In this tllesis，porous polymer and llierarcllically porous rnelIl_branes are pr印ared by gupercritical nuids and hyper-crosslirll(ir培reaction．The maill results are sun】加ar娩ed as I’0Uows． Inspired by the block copolyIner self-嬲sembly and S1lpercritical nuid selectively sv旧llir唱，porous s伽lcture was success如lly血roduced缸o polyst)，rene／surf．act锄t filIlls．The i11仃oduction of surfactant call cause a solubility di位renCe when e冲osed to ca^on dioxide e)【pallded Inethanol liqHid and then the surf．act趾ts were selectiVely s、№Uen by methan01．The e彘cts of e冲eriInental conditions such as kms and 锄ount of s砒f-actams，temperanlre，pressure，aIld d印ressur娩ation rate on the Ino印hology of the polyst)，rene films．The a、，erage cell di锄eter of polystyrene shows no obVious d“诧rellce at di彘rent tenlperature a11d pressure． Increash唱 the temperatl叫e or pressure，ceU deIlsity first iIlcreased and then decreased．An additive 锄ount of 3．0吼％was a11 optimum to achieVe ma)【imum ceU denSity．Four l【inds of sur矗lCtallts wim different HLB(Hydropllilic-Lipophilic Balance)Value are used to pr印are porous polyst)，rene．nv0 sl盯f-actaults with 10wer卸已B value sho、Ⅳed cell stmcture i11血crorneter scale while the others with lligher}玎mⅦlue showed cell stmcture iIl mnonleter scale．The surfactant i11 the polystyrene acted as a teInplate for selectively swelliI培．Moreover，we applied tms method to polylactiC acid，wKch also sh