钼基化合物与碳复合载体载铂电催化剂的构建及性能研究-环境科学专业论文.docxVIP

优秀毕业论文 精品参考文献资料 AbstractDirect Abstract Direct methanol fuel cell(DMFC)is considered as one of the promising energy conversion device for portable electronic equipment and electric vehicle．This is because it uses methanol as fuel and has low cost，high energy density,renewable and easy storage and transportation．However,some challenges still need to be overcome for the anode Pt-based catalyst of DMFC，such as the high cost，CO poisoning and support corrosion．All the factors restrict the large—scale commercialization of DMFC． Therefore，mixing molybdenum compounds with Vulcan XC一72 carbon black as hybrid support into the DMFC anode catalyst can effectively improve the above problems，it still carl not reach the performance requirements of commercial ization．In this regard，M003 nanorods，Ce02一M003 composite nanorods and MoS2 nanoparticles were prepared in this work to expect to improve the performance of M003，and electrochemical oxidation performance of methanol were also studied for these three kinds of molybdenum—based compounds are mixed with Vulcan XC．72 carbon black． (1)M003 nanorods were prepared by a simple hydrothermal method．In order to determine the suitable reaction conditions of preparing M003 nanorods，the influences of the hydrothermal reaction temperature and time on the morpho logy were studied．Based on the study,the suitable reaction conditions to prepare M003 nanorods were regarded as hydrothermal reaction at 1 80。C for 24 h。The prepared M003 nanorods was very smooth and clean on the surface with the length of 6 gm and the width of 250 nm．The results of electrochemical tests showed that the current density of methanol electrochemical oxidation of Pt／MoOsnan。r。d—C catalyst is 442 mA mg-l， the catalyst shows good resistance to CO poisoning and electrochemical stability． (2)In order to futXher enhance the CO—catalytic effect of M003 nanorod on 万方数据 黑龙江大学硕士学位论文methanol 黑龙江大学硕士学位论文 methanol electrooxidation，the Ce02一M003 composite nanorods with different Ce：Mo