《含氮四羧酸配体配位聚合物的合成及性质研究论文》-毕业论文设计（可用）.docVIP

含氮四羧酸配体配位聚合物的合成及性质研究 摘要: 随着现代测试技术的发展及量子力学理论技术的应用，现代配位化学以惊人的速度迅猛发展，成为化学、物理学、生命科学、材料科学、信息科学等多种学科的研究热点。配位聚合物是通过配体和金属离子的自由组装而形成，它属于配位化合物中的一类。配位聚合物具有性质独特、结构多样化、不寻常的光电效应、可使用众多的过渡金属离子等特点,所以在非线性光学材料、磁性材料、超导材料及催化和生物活性等诸多方面都有很好的应用前景[1-4]。含氮羧酸类配体因同时具有N、O配位原子,其中氧原子易与硬金属离子配位，而氮原子易与软金属离子配位，所以表现出对金属离子选择性的配位能力，可以按照设想的方式与金属离子形成稳定的单核、双核及杂多核桥联配合物。本文介绍了以4,4’-((2,2’-(ethane-1,2-diylbis(carboxymethyl)azanediyl))bis(acetyl))bis(azanediyl))dibenzoic（H4L）作为反应物，与过渡金属通过水热法自组装得到了2个配位聚合物，并对所合成配位聚合物的合成规律、结构、性质进行了研究。 关键词：配位聚合物，水热合成，金属离子，多羧酸 Nitrogen-containing polycarboxylic acid ligands Synthesis and Properties of Polymers Qinghui chen Ming hu Abstract: With the development of testing technology and the application of quantum mechanics theory, Modern coordination chemistry develops with a amazing rapid, and it has became the science hotspots of various disciplines, such as chemistry, physics, life sciences, materials science and information technology. Coordination polymers is formed through free assemble between ligand and metal ions,it belongs to the coordination compounds. Coordination polymers have many characteristics, such as unique properties, structural diversity, unusual photoelectric effect, so it has a good prospect in the nonlinear optical materials, magnetic materials, superconducting materials and catalytic and biological activity and other aspects. Pyridine-carboxylate ligands hold nitrogen atoms which tend to binding to hard metal ions and oxygen atoms which are prone to link soft metal ions as well as. Thus, the kind of ligands possesses high choiceness to metal centers and may form stable mononuclear, dinuclear or heteronuclear compounds as expected fashions.So here we take the 4,4’-((2,2’-(ethane-1,2-diylbis(carboxymethyl)azanediyl))bis(acetyl))bis(azanediyl)) dibenzoic as reactant,it self-assemble with the transition metal by hydrothermal method and obtain two coordination polymers,we hav