热镀锌板上-APT硅烷自组装膜的制备及相容性-Journalof.PDFVIP

第32 卷第7期 东 北 大 学 学 报 ( 自 然 科 学 版 ) Vol32, No. 7 2 0 1 1 年 7 月 Journal of Northeastern U ni ersity( Natural Science) Jul. 2 0 1 1 - APT 王 雷, 刘常升, 石 磊 ( 1. , 110819) : - APT , - APT - GPT Si O Zn , Si O Si , , 10 h , 10 h - APT - GPT : ; ; ; ; : T G 174 : A : 1005-3026( 2011) 07-0956-04 Synthesis and Compatibility Evaluation of Self- assembled Monolayers of -APT Silane on Hot- Dip Galvanized Steel WAN G Lei, LI U Chang-sheng, SHI Lei ( Key Laboratory for Anisotropy T exture of Materials, Ministry of Education, Nort heastern Uni ersity, Shenyang 110819, China. Corresponding author : WA NG Lei, E-mail: mailwl @ 163. com) Abstract The synthesis of -APT silane self-assembled monolayers ( SAMs ) on hot-dip gal anized steel( HDG ) and the SAM s compatibility w ith -GPT silane w ere in estigated by electrochemical impedance spectroscopy ( EIS) and contact angles analysis. The results show ed that the SAM s of the -APT silane are deposited on HDG surfaces. First, the SiOH groups of - APT are absorbed quickly onto the HDG surfaces to form Si O Zn. Then Si O Si co alent bonds are formed betw een the -APT silane molecules and the zinc surface, releasing w ater as a byproduct. The SAM s become stable and the compatibility betw een the SAM s and -GPT silane is good w hen HDG sheet is immersed in the silane for 10 hours. After that the SAMs is no continuity as a mishmash. Key words silane; SAM s ( self-assembled monolayers) ; EIS; hot-dip gal anized steel sheet; compatibility , ,