改性膨润土的制备表征及吸附性能的研究.DOCVIP

CTMA插层改性膨润土对甲基橙吸附动力学与热力学 任建敏, 吴四维, 张永民 (重庆工商大学环境与生物工程学院，重庆400067) 摘要:用十六烷基三甲基铵(CTMA) 阳离子对钠基膨润土通过离子交换插层改性，采用X射线衍射(XRD)和红外光谱( IR)对CTMA改性膨润土结构表征，在100%的离子交换下，其d001比钠基膨润土增大7.54?，红外光谱显示CTMA改性膨润土的-OH伸缩与弯曲二振动强度明显低于钠基膨润土。用甲基橙水溶液为染料废水模型物，考察了303 K、323 K 和 343 K温度下，CTMA改性膨润土对甲基橙的吸附性能，对吸附实验数据运用相关数学模型拟合，得出该等温吸附平衡符合Langmuir与Freundlich二吸附模型，整个吸附过程更适合准二级动力学；通过计算不同温度各热力学参数ΔG°、ΔH°和ΔS°，证实该吸附过程为一自发的放热物理吸附. 关键词：膨润土；CTMA；表征；吸附；甲基橙 中图分类号:X703.5 文献标识码:A Kinetics and Thermodynamics of Adsorption of Methyl Orange onto Intercalated CTMA-Bentonite. REN Jian-min,WU Si-wei, Zhang Yong-ming (Environment and Biological School, Chongqing Technology and Business University，Chongqing 400067,China) Abstract: The intercalated CTMA-bentonite was prepared by Na-bentonite cation exchanged with cetyltrimethylammonium. Product was characterized by XRD and IR techniques. The d001 spacing value of CTMA-bentonite is 7.54? larger than that of Na-bentonite at 100% of the cation exchange capacity. The IR spectrum showed that the intensities of OH stretching and bending vibrations of CTMA-bentonite decreased greatly comparing to untreated Na-bentonite. Batch experiments were carried out at 303 K、、 323 K and 343 K to obtain the sorption isotherms of methyl orange on CTMA-bentonite. The results show that the sorption isothermal data could be well described by Langmuir and Freundlich model accurately. The dynamical data fit well with pseudo-second-order kinetic model. Thermodynamic parameters such as changes in the free energy (ΔG0)、、the enthalpy (ΔH0) and the entropy (ΔS0) were also evaluated. The overall adsorption process of methyl orange on CTMA-bentonite was spontaneous, exothermic physisorption. The CTMA-bentonite could be employed as low-cost alternatives to activated carbon in wastewater treatment for the removal of corlor which comes from textile dyes. Key words:Bentonite;CTMA;Characterization;Adsorption;Methyl Orange 印染工业废水有机物含量高、色度深、可生化性差、排放量大、水质复杂，染料的降解产物多为联苯胺类等一些致癌的芳香类化合物，会严重的影响人体健康，已成为难以治理的工业废水之一[