改性回收聚酯pet瓶料吹塑薄膜成型工艺研究材料科学与工程专业论文.docxVIP

北京化工大学硕士学位论文节加工工艺参数，最终确定引发剂DCP、共单体St，接枝反应温度 北京化工大学硕士学位论文 节加工工艺参数，最终确定引发剂DCP、共单体St，接枝反应温度 150．180。C，双螺杆转速30r／min，制得的GMA—g—HDPE的接枝率为 1．62％，扩链后rPET／HDPE．g—GMA共混物的熔体流动速率由 15．759／10min降至7．389／10min；HDPE／EVA增强体制备时，控制 HDPE与EVA配比10：3，共混温度110—170。C，转速30r／min，经DSC 和SEM表征，HDPE和EVA具有良好的混溶性，扩链后 rPET／皿PE／EVA共混物的熔体流动速率降至6．689／10min。 改性rPET吹塑薄膜的制备，通过不同配方的比较，选择扩链后 rPET与GMA—g—HDPE增强体最佳配比100：10，扩链后rPET与 HDPE／EVA增强体最佳配比100：3：10。反复调节吹塑工艺参数，经 挤出机熔融吹塑工艺，得到扩链后rPET／GMA．g．HDPE薄膜制品和 扩链后rPET／HDPE／EVA薄膜制品，最终确定吹胀比为3，牵引速度 为5m／min条件下，扩链后rPET／GMA—g—HDPE薄膜的拉伸强度与撕 裂强度高达44．16MPa和188．96KN／m，透光率达87％。在吹胀比为 3．5，牵引速度为6．5m／min条件下，扩链后rPET／GMA—g．HDPE薄膜 拉伸强度与撕裂强度高达36．84MPa和138．25KN／m，透光率达85％。 关键词：回收聚酯(rPET)，三元共聚物，扩链反应，增强体，吹 塑成膜 万方数据 AbstractRESEARCH Abstract RESEARCH ON MoDIFICATIoN oF RECYCLED PET AND PRoCISSl0N ARTS OF BLoW MoLDING FILMS ABSTRACT With polyester PET production increasing rapidly,more and more PET bottles waste came into the nature．It is a common challenge for researches to find a new way recycling the PET bottles．This paper researchs on modification of recycled polyester(rPET)by adding terpolymer SAG(styrene-acrylonitrile-glycidyl methacrylate)as chain extender．The chain extension of rPET was seccessful by the break—down of linear chain structure during the twin—screw extrusion，and a new resin with branched chain structure was generated with lower degree of crystallinity．To enhance melt strength，glycidyl methacrylate(GMA) grafted high density polyethylene(GMA—g—HDPE)and HDPE／EVA blend were blended with chain extended rPET matrix respectively．Fanilly,chain extended rPET／GMA·-g·-HDPE blends and chain extended rPET／E、厂A／HDPE blends were blow molded into films．The film with high strength and transparency was used widely in industrial packaging and motor wire insulation layer．In addition，the thin lII 万方数据 万方数据 万方数据 北京化工大学硕士学位论文film 北京化工大学硕士学位论文 film had consistent two—way performance，instead of film products．by complicated two—way tensile process． In the chain extension of rPET,SAG compare