分子筛的改性对无卤阻燃聚丙烯复合材料燃烧性能的影响材料科学与工程专业论文.docxVIP

北京化工大学硕士学位论文观测，发现4A．L主要通过促进聚合物基体交联成炭来提高其阻燃效果。 北京化工大学硕士学位论文 观测，发现4A．L主要通过促进聚合物基体交联成炭来提高其阻燃效果。 这是因为4A．L中的lewis酸能与PP热解后生成的芳香族化合物发生取代 反应，使得链段间发生交联，进而促进了聚合物成炭。PP／IFR／4A—L(78／20／2) 的LOI达到33．7％，拉伸强度为26 Mpa。 其次，本课题将稀土元素镧(La)和钬(Ho)引入到分子筛中，得 到4A．La和4A．Ho分子筛，以增加L酸酸性点，提高催化成炭性能。X 射线荧光光谱分析(Ⅺ强)表明La和钬Ho己成功地引入到分子筛中。 XRD的分析结果表明单纯的离子交换并不会明显改变分子筛的骨架结构， 但其晶面间距减小、结晶度降低。TGA的结果表明4A．La分子筛的吸附 作用要好于4A．Ho分子筛，可以储存更多的结晶水。LOI、UL．94和锥形 量热分析结果表明4A．La与IFR间存在协效阻燃作用且生烟量降低。加 入2叭．％4A．La后复合材料的LOI最高达到32．7％，UL．94也达到V 1 级别，与IFR的协效率达到1．81。 最后，本课题将第四周期的5种金属元素Ca、Co、Ni、Cu、Zn引 入到分子筛中并通过高温煅烧得到4A．Me，制备了含有不同分子筛的5 种PP／IFR体系共混复合材料。通过LOI和UL．94测试，发现PP／IF舭A_Cu 的阻燃效果最好，锥形量热分析显示4A．Cu能在燃烧初期促进基体成炭， 从而达到阻燃的目的。残炭的SEM和EDS表征表明4A．Cu可以使得更 多的C和N留在残炭中，使得炭层更质密更稳定，隔绝基体和氧气，阻 止燃烧进一步蔓延。 关键词：聚丙烯，分子筛改性，膨胀型阻燃剂，阻燃机理，协同效 Ⅱ 万方数据 摘要应 摘要 应 Ill 万方数据 北京化工大学硕士学位论文Effects 北京化工大学硕士学位论文 Effects of modified zeolite on fire performance of halogen free polypropylene composites ABSTRACT As one of the five general plastics，polypropylene(PP)has been widely used in daily life．However,PP is highly flammable and aplenty of smoke is generated during burning．Intumescent flame retardant(IFR)is often used in PP composite because of their environmental—friendly．Synergist，such as montmorillortite，kaolinite，and zeolite，is widely added to the IFR system to enhance the efficiency of flame retardancy． In this work,zeolite in association with a conventional IFR system containing ammonium polyphosphate and pentaerythritol was introduced to enhance the flame retardancy of PP．Different positive ions were introduced into zeolite by ion exchange method to improve the catalytic performance of zeolite．The effect and mechanism of modified zeolite on the—synergism of flame retardant with IFR were also investigated． 1．Zeolite contained Lewis acid sites(4A-L)was prepared by ion—exchange and calcination．The crystallinity characterization using X—ray diffraction(XRD)and chemical structure characterization by Fourier transform infrared(FTIR)spectroscopy showed that Lewis acid sites