二维层状复合电极材料的制备及其超电性能的研究应用化学专业论文.docxVIP

of of binary CoNi2S4 electrode is achieved with 96．3％of the initial capacitance 900 consecutive cycles at 1 5 A／g．Moreover,the columbic efficiency consistently remains above 94．3％within 900 cycles．The fine specific capacitance and 900d cycling stability demonstrate that the mesoporous CoNi2S4 electrode has potential applications in supercapacitors． Ni-MOFs@NiSx composite materials werg synthesized via stepwise hydrothermal method involving precipitation and in-situ sulfurization of Ni—MOF．By controlling Ostwald ripening reaction times during the sulfurization process，Ni·MOFs@NiSx with tailored NiSx nanostructure have been fabricated as electrode materials for electrochemical capacitor application．This unique three·dimensional structure promoted the charge transfer and the diffusion of the electrolyte ions，thus improving the efficiency of the material．The experimental results show that the Ni-MOFs@NiSx materials exhibits much higher specific capacitance of 716 F／s than that of Ni-MOFs(124．5 F／g)in 6 mol／L KOH at rate of 5 mV／s，The excellent cycling stability of Ni-MOFs@NiS。electrode is achieved with 86．3％of the initial capacitance 1 000 consecutive cycles at 1 0 A／g，which is higher than that of Ni—MOFs(，嗡1．4％)．The high specific capacitance and good cycling stability demonstrate that the Ni-MOFs@NiS。electrode has potential application in supereapaeitors． Ke]一vord：two-dimensional(2D)materials，layered double hydroxides(LDHs)，layered metaldichalcogenides(TMDs)，graphene composite materials，supereapacitor． III 万方数据 论文中的插图及附表清单图1．1石墨烯独特的原子结构示意图 论文中的插图及附表清单 图1．1石墨烯独特的原子结构示意图 ．．4． 图1．2石墨烯复合碳管前后的结构示意图 ．．5． 图1．3石墨烯复合金属化合物的结构模型：(a)锚定式(b)包裹式(c)胶囊式(d)--N治式 (e)层状式(f)混合式 ．．5． 图l-4层状双羟基氢氧化物材料的层状结构 ．．7． 图1．5(a)CoS2和(b)C09S8的晶体结构图【911 ．8． 图1-6化学法制各高分散水溶性石墨烯溶液 ．．9． 图1．7水热法制备Ni3S2和C03S4的示意图 ．．10． 图1．8本论文的技术路线图 ．16． 图2．1氧化石墨烯的制备流程图 ．19． 图2．2镍钴金属氢氧化物样品的制备工艺流程图 ．19． 图2．3石墨烯／镍钴双金属氢氧化物(rGO／Ni．Co LDHs)复合材料的的制备流程图 ．．．20． 图2-4(a)所制备样品的XRD谱图：(a)LDHs，(b)GO，(c)LDHs：GO(1：3)，LDHs：GO(1：2)， LDHs：GO(1