p型bi2te3基制冷晶棒加工废料的资源化处理与热电性能优化冶金工程专业论文.docxVIP

关键词：热电材料；热电性能；加工废料；废料回收；通电加压烧结n 关键词：热电材料；热电性能；加工废料；废料回收；通电加压烧结 n 万方数据 AbstractThermoelectric Abstract Thermoelectric material iS a kind of new functional material and lt can realize the direct conversion between heat energy and electric energy，which has broad application prospects in the field of thermoelectric refrigeration and thermoelectric power generation．In view of the present situation that high scrap rate in the processing and production of Bi2Te3 based thermoelectric materials in the semiconductor refrigeration industry，and the drawbacks of existing waste recycling technology such as environmentally unfriendly，process complicated，long cycle and high cost，a new technology for recovering processing waste of Bi2Te3 based refrigeration crystal bar was proposed．The impurities in the waste were effectively removed through washing，carbonization，smelting and other processes．Then the bulk materials with excellent properties were prepared by composition adjustment and Resistance Pressing Sintering technique．In addition，Bi2Te3 based alloys have been widely used in the field of thermoelectric refrigeration as the best thermoelectric material near room temperature，but their applications in thermoelectric power generation are relatively backward．The temperature dependence of the electric．thermal transport properties and the figure of merit of Bi2Te3 based thermoelectric materials with different antimony content were studied with the energy band theory．The thermoelectric properties of P-type Bi2Te3 based alloy at high temperature were optimized．The results were obtained as follows： 1、After simple ultrasonic cleaning and melting process for the processing waste fragments，the impurities in the fragments Can be removed and the high purity Bi2Te3 based alloy rod can be obtained．The comprehensive performance of the sample in the whole temperature region was significantly improved after the composition adjustment．The ZT values of Bi0．36Sbl．64Te3，Bi0．4Sbl．6Te3 and Bi0