改性沸石膨润土对重金属离子的吸附性能研究环境工程专业论文.docxVIP

山东建筑大学硕士学位论文利用制备的壳聚糖交联沸石、膨润土微球(CTS／IL／Z、CTS／IL／B)，分别吸附CC+、 山东建筑大学硕士学位论文 利用制备的壳聚糖交联沸石、膨润土微球(CTS／IL／Z、CTS／IL／B)，分别吸附CC+、 Cr2072。和Pb2+，试验发现CTSflL／Z、CTS／IL／B对Cu2+的吸附容量分别为118．8 mg／g，125．5 rag／g；对Pb2+的吸附容量分别为324．48 mg／g，250．0 mg／g。两种吸附剂对Cr2072。的吸附 量相比于未改性沸石、膨润土提高了近5倍。通过探究pH值对去除率的影响发现：当 pH为4时，CTS／IL／Z、CTS／IL／B对pb2+的去除率分别达到98％和99％；当pH为6时， CTS／IL／Z、CTS／IL／B对Cu2+的去除率均达到99％以上；对于Cr2072。的吸附，酸性条件下 好于碱性条件下。共存体系中，CTS／IL／Z、CTS／IL／B对不同重金属离子有选择吸附性， 其吸附量大小顺序为：Cu2+pb2+Cr2072。。本试验采用酸再生法对吸附剂进行再生，试 验发现用0．1 mol／LH2SO。对吸附剂的再生效果较好。 试验发现：表面活性剂改性沸石与未改性沸石对pb2+和Cr20d’的吸附性能不同。通 过Zeta电位、FTIR及XRD等测定改性沸石、未改性沸石表面及内部结构特征，证明表 面活性剂以双分子层形式结合到沸石表面，从而使沸石的电负性发生改变，并提出静电 吸附机理可能是改性沸石选择性吸附不同类型金属离子的主要原因。CTS／Ⅱ，／Z、CTS／几／B 对Cu2+、Pb2+和Cr2072。的吸附量较未改性沸石、膨润土有较大提高，用FTIR、SEM、 Zeta电位等对吸附剂的表征进行分析发现，CTS／IL／Z、CTS／IL／B对不同重金属离子的吸 附作用包括：静电作用；螯合作用。 关键词：改性沸石、膨润土；重金属离子吸附；静电吸附；螯合作用 II 万方数据 山东建筑大学硕士学位论文The 山东建筑大学硕士学位论文 The adsorption properties of modified zeolRes and modified bentonite on heavy metal ions JiangJiahui(Environmental Engineering) Directed by WuDaoJi ABSTRACT This research mainly discusses two aspects：the CPB and CTAMB modified zeolites were used to adsorb the Cr2072-Pb2+,and different adsorption effect on the different metal ions had been studied；the Zeta potential，infrared spectra(FTIR) and X-ray diffraction(XRD)of the modified and unmodified zeolites had been analyzed；the effect of the pH had been studied．The chitosan，zeolite，bentonite and ionic liquid were used as material to prepare the microspHeres that chitosan crosslinked zeolite and bentonite(CTS／IL／Z， CTS／IL／B)． And the adsorption capacity of Cu2+、Cr2072’和Pb2+on CTS／IL／Z、CTS／IL／B were studied； Its adsorption capacity of the heavy metal ions was affected by the pH and dosage also were explored；the Zeta potential，infrared spectra(FTIR)and scanning electron microscope(SEM)of the modified and unmodified zeolites had been analyzed；the adsorption mechanism also had been analyzed；On this basis， regeneration process of adsorbent in the acid solution was stu