钙在镁合金熔炼中的阻燃机理-JournalofNortheasternUniversity.PDF

30 4 ( ) Vol130,No.4 2009 4 Journal of Northeastern University( Natural cience) Apr. 2 0 09 , , , ( 东北大学 材料与冶金学院, 宁 沈阳 110004) : 熔炼了钙的质量分数为01 5%~ 510% , 铝的质量分数为91 0% 的10 种镁合金,研究了Ca 的加 入对合金阻燃效果的影响 分别取定量的 10 种合金在700 e 的高温下进行氧化增重的测量, 并对合金表面的 # 氧化形貌进行了观察 实验结果表明: 镁合金加入钙后, 其表面在高温下生成了CaO 及少量MgO 的复合致密 # 氧化膜, 这层氧化膜隔绝了空气, 阻止了镁的燃烧; 当钙的质量分数为31 5% 时, 可起到良好的阻燃效果# : 镁合金; 阻燃; 钙;氧化膜; CaO : TG 113 : A : 10052 3026(2009)04 On the Ignition2Pr oof Behavior of Ca Dur in g Mg Alloy Melt in g J I H ai2bin , YAO Gua ng2chun , LI U Le2tia n , Z U Guo2yin ( chool of Materials Metallurgy, Northeastern University, henyang 110004, China. Correspondent : JI Ha2i bin, E2mail: jihaibin1023 @ 163. com) Abstr act : Investigates the effect of Ca addition on the ignition2proof behavior of 10 kinds of molten Mg alloys, in which the Ca content was 0. 5wt%~ 5. 0wt% and Al content 9. 0wt% . All the specimens of equal weight taken from those alloys were measured at 700 e for their weight increments due to oxidation, and their oxidized surface morphologies were observed. The results revealed that a dense composite CaO film containing a bit of MgO grows up on alloy surface at high temperature after adding Ca to the alloy, and the film is thus isolated from air to prevent Mg from burning. The ignition2proof effect is favorable if the Ca content in Mg alloy is 3. 5wt%. Key words: Mg alloy; ignition2proof; Ca; oxide film; CaO 镁合金具有比重小、比强度和比刚度高、阻尼 炼过程中形成致密的氧化膜, 便可阻止镁的氧 [ 5] 性能好、切削加工性能好等优点 镁合金主要应用