胺类离子液体的制备及其脱硫性能实验研究化学工程专业论文.docxVIP

万方数据 万方数据 河北科技大学硕士学位论文 11 AbstraetAbstract Abstraet Abstract The atmospheric pollution is increasingly serious with the rapid development of national economy,and the control of S02 pollution has become a top priority．Traditional desulfurization technology has some disadvantages：Causing corrosion of equipment, producing waste of liquid and residue，resulting secondary pollution to environment and the waste of sulphur resources．Ionic liquids have attracted the attention of many scholars because of their excellent characteristics，such as negligible vapour pressure，high boiling point，high stability,good desulfurization efficiency and regeneration performance．But the disadvantages of hi曲viscosity and cost of ionic liquids limit their application in industry．Immobilization of Ionic liquids on porous materials or mixed with other solvent can enhance the desdfurization effect and solve these problems． In this paper,two kinds of ionic liquid，trioct)rlamine hydrochloride and trioctylamine sulfate，were synthesized and characterized by FT-IR,1 H NMR and TG The desulfurization performance of the ionic liquids were investigated．The saturated absorption capacity Was 0．2509 s02／g IL(1．763mol S02／mol rE)for trioctylamine sulfate and 0．357 g S02／g IL(2．1 74mol S02／mol IL)for trioctylamine hydrochloride，respectively． After six continuous adsorption—desorption cycles，the absorption performance of the ionic liquids remain invariant，which illustrate that the ionic liquids have good reuse performances．The ionic liquids synthesized in this paper still have good absorption effect for the gas with low concentration of S02．When S02 concentration is 0．2％，the saturated absorption capacity Was 0．0539 S02／g IL for triocty7lamine hydrochloride and 0．0379 s02／g IL for trioctylamine sulfate，respectively． Binary systems of IL—DMSO were given by mixing DMSO诵th ionic liquids，and desulfurization performance of the binary systems were investigated．The desulfurization performance of the binary system is gr