掺氟钾羟基磷灰石粉体的制备及性能研究材料科学与工程专业论文.docxVIP

对F。的吸附为单分子层吸附，经计算得出的二级吸附速率常数k2=7．526×10。 对F。的吸附为单分子层吸附，经计算得出的二级吸附速率常数k2=7．526×10。 g-(mg·min)～，最大吸附容量为3 1．55 mg-g～。 (4)实验发现，FKHAp材料在模拟体液中能够诱导新的磷灰石沉积 层，具备一定的生物活性，在HAp中共掺入F和K可以明显提高HAp的 生物活性。 关键词：0【一磷酸钙，钾羟基磷灰石，吸附，氟掺杂，生物活性测试 Il 万方数据 PREPARATIoN PREPARATIoN AND PRoPERTIES STUDIES oF PoTASSIUM FLUoRINE SUBSTITUTE HYDROXYAPATITE ABSTRACT Hydroxyapatite(HAp)possesses a certain bioactivity，it can release the ions to help the tooth mineralization and also can be used to plug the tooth surface damage which is eroded by the acid to reduce the sensitivity of the teeth．The addition of fluoride and potassium in HAp can not only improve the mechanical properties and biological activity，but also improve the health of the oral cavity． Therefore，how to control the process parameters to prepare the fluorine and potassium doped HAp materials with good biological activity is the outstanding problem that needs to be solved． In this paper，calcium nitrate and phosphoric acid were used as rawmaterials， and ammonia was applied as the pH adjusting agent．First，the calcium phosphate was prepared by precipitation method，then the powder of calcium phosphatewas sintered in a muffle furnace at different temperatures，thus a-Ca3(PO,)2andpower were obtained．At last，the 13t—TCP powder was hydrated and the hydration product of deficient calcium hydroxyapatite Was added to the solution of KOH，thus was potassium(KHAp)prepared．The atomic absorption spectrophotometry，theX·ray diffraction scanning electron microscope，the fourier infrared spectrometer and the X-ray energy spectrum were used toanalysis the characterize of the prepared material．Then KHAp powder was added into the solution that contain the ions fluoride，the fluorine ion concentration in solution was determined by selective electrode method．By firing the the adsorption kinetics equation and adsorption isotherm equation，the influences of the solution pH and amount of powder on the adsorption fluorine ion property of the powder was researched，at